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TDI型PU/HGM复合材料的制备与性能研究

巩汉炜 张育林 乔文强 王植源

塑料科技2026,Vol.54Issue(1):57-61,5.
塑料科技2026,Vol.54Issue(1):57-61,5.DOI:10.15925/j.cnki.issn1005-3360.2026.01.011

TDI型PU/HGM复合材料的制备与性能研究

Preparation and Properties Study of TDI Type PU/HGM Composites

巩汉炜 1张育林 1乔文强 1王植源1

作者信息

  • 1. 大连理工大学化工学院高分子材料系,辽宁 大连 116024
  • 折叠

摘要

Abstract

Nine composites were prepared using three different chain extenders,namely 1,4-butanediol(BDO),4,4'-methylenebis(2-chloroaniline)(MCOA),and 4,4'-methylenebis(3-chloro-2,6-diethylaniline)(MCDEA),along with TDI-PTMEG prepolymer and hollow glass microspheres(HGM).The effects of HGM on the properties of polyurethane elastomers were investigated.The results showed that the addition of HGM significantly reduced the density of the composites and increased their hardness,but also decreased the tensile strength and elongation at break to some extent.However,HGM modified with a silane coupling agent(KH550)could ensure better mechanical properties of composites while maintaining a low density.The addition of modified HGM could reduce density of MCOA system by 21.0%,increase temperature of 50%weight loss by about 10℃,and achieve a tensile strength of 27.61 MPa.

关键词

聚氨酯弹性体/空心玻璃微珠/甲苯二异氰酸酯

Key words

Polyurethane elastomer/Hollow glass microspheres/Toluene diisocyanate

分类

化学化工

引用本文复制引用

巩汉炜,张育林,乔文强,王植源..TDI型PU/HGM复合材料的制备与性能研究[J].塑料科技,2026,54(1):57-61,5.

塑料科技

1005-3360

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