中国钼业2026,Vol.50Issue(1):85-93,9.DOI:10.13384/j.cnki.cmi.1006-2602.2026.01.010
氧化铪弥散强化钨合金的组织与力学性能研究
Microstructure and mechanical properties of hafluim oxide dispersion-strengthened tungsten alloys
摘要
Abstract
Hafnium oxide(HfO2)strengthened tungsten(W)alloys with excellent strength and plasticity was prepared by freeze-dr-ying and pressureless sintering.Firstly,uniform W/HfO2 composite nanopowder was in-situ synthesized by the"freeze-drying-hydrogen reduction"process.After being formed by uniaxial pressing at 550 MPa and sintered at 1850℃for 2 hours,W-(0.5%~10%,mass fraction)HfO2 alloys with a density of over 95%was prepared.Unlike the second phase refinement effect of traditional dispersion strengthening materials,the HfO2 particles in W-10%(mass fraction)HfO2 tend to aggregate at the grain boundaries and grow up to 640 nm.The high volume fraction and coarse particle size of the second phase enable the W alloys to achieve the optimal match of strength and plasticity,with a yield strength as high as 2 090 MPa and a fracture strain of 21.0%.Compared with pure W,it has in-creased by 81%and 84%respectively.The in-situ synthesis method of composite powder adopted in this paper provides a way to regu-late the microstructure of the second phase.By regulating the particle size,distribution and volume fraction of the second phase,it is expected to further improve the matching of strength and plasticity of W alloys.关键词
弥散强化/钨合金/粉末冶金/力学性能/强韧化Key words
dispersion-strengthened/tungsten alloy/powder metallurgy/mechanical properties/strengthening and toughening分类
通用工业技术引用本文复制引用
程行,李星宇,章林,阙忠游,刘俊明,郭晨光,秦明礼,曲选辉..氧化铪弥散强化钨合金的组织与力学性能研究[J].中国钼业,2026,50(1):85-93,9.基金项目
国家自然科学基金(52504390,52474387,52374366) (52504390,52474387,52374366)
博士后创新人才支持计划(BX20230043) (BX20230043)