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CO2加氢制备低碳烯烃的研究进展

张倩 王森 张天釜 许林 董梅 樊卫斌

燃料化学学报(中英文)2026,Vol.54Issue(3):1-14,14.
燃料化学学报(中英文)2026,Vol.54Issue(3):1-14,14.DOI:10.3724/2097-213X.2025.JFCT.0026

CO2加氢制备低碳烯烃的研究进展

Recent advances in CO2 hydrogenation to light olefins

张倩 1王森 2张天釜 3许林 3董梅 2樊卫斌2

作者信息

  • 1. 中国科学院山西煤炭化学研究所煤炭高效低碳利用国家重点实验室,山西太原 030001||中国科学院大学,北京 100049
  • 2. 中国科学院山西煤炭化学研究所煤炭高效低碳利用国家重点实验室,山西太原 030001
  • 3. 国家电投集团科学技术研究院有限公司,北京 102209
  • 折叠

摘要

Abstract

The successful development and application of CO2 hydrogenation to light olefins can not only alleviate the environmental issues caused by the massive emission of greenhouse gases,but also open up a new way for the preparation of important high-value chemicals.Due to the chemical inertness of CO2 molecules,selectively activation and conversion of CO2 into target light olefins remain highly challenging.In this work,we review the current research progress in the hydrogenation of CO2 to light olefins,with a focus on analyzing the advantages and disadvantages of the Fischer-Tropsch synthesis(CO2-FTO)route and the methanol intermediate(CO2-MTO)route.The key factors,such as the type of additives,the structure of the carrier and the concentration of surface defect sites,affecting the activation of CO2 and the formation of light olefins are discussed in detail.Meanwhile,essential role of the pore structure and acidity of zeolites in conversion of methanol intermediates to olefins is analyzed.

关键词

CO2加氢/低碳烯烃/费托合成路线/甲醇中间体路线

Key words

CO2 hydrogenation/light olefins/Fischer-Tropsch synthesis route/methanol intermediate route

分类

化学化工

引用本文复制引用

张倩,王森,张天釜,许林,董梅,樊卫斌..CO2加氢制备低碳烯烃的研究进展[J].燃料化学学报(中英文),2026,54(3):1-14,14.

基金项目

Supported by National Key R&D Program of China(2023YFB4103102)and National Natural Science Foundation of China(22272195,22322208,U22A20431).国家重点研发计划(2023YFB4103102)和国家自然科学基金(22272195,22322208,U22A20431)资助 (2023YFB4103102)

燃料化学学报(中英文)

2097-213X

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