燃料化学学报(中英文)2026,Vol.54Issue(3):1-14,14.DOI:10.3724/2097-213X.2025.JFCT.0026
CO2加氢制备低碳烯烃的研究进展
Recent advances in CO2 hydrogenation to light olefins
摘要
Abstract
The successful development and application of CO2 hydrogenation to light olefins can not only alleviate the environmental issues caused by the massive emission of greenhouse gases,but also open up a new way for the preparation of important high-value chemicals.Due to the chemical inertness of CO2 molecules,selectively activation and conversion of CO2 into target light olefins remain highly challenging.In this work,we review the current research progress in the hydrogenation of CO2 to light olefins,with a focus on analyzing the advantages and disadvantages of the Fischer-Tropsch synthesis(CO2-FTO)route and the methanol intermediate(CO2-MTO)route.The key factors,such as the type of additives,the structure of the carrier and the concentration of surface defect sites,affecting the activation of CO2 and the formation of light olefins are discussed in detail.Meanwhile,essential role of the pore structure and acidity of zeolites in conversion of methanol intermediates to olefins is analyzed.关键词
CO2加氢/低碳烯烃/费托合成路线/甲醇中间体路线Key words
CO2 hydrogenation/light olefins/Fischer-Tropsch synthesis route/methanol intermediate route分类
化学化工引用本文复制引用
张倩,王森,张天釜,许林,董梅,樊卫斌..CO2加氢制备低碳烯烃的研究进展[J].燃料化学学报(中英文),2026,54(3):1-14,14.基金项目
Supported by National Key R&D Program of China(2023YFB4103102)and National Natural Science Foundation of China(22272195,22322208,U22A20431).国家重点研发计划(2023YFB4103102)和国家自然科学基金(22272195,22322208,U22A20431)资助 (2023YFB4103102)