燃料化学学报（中英文）2026，Vol.54Issue(3)：92-104,13.DOI:10.1016/S1872-5813(25)60610-4
非金属刷状三维氮化碳驱动高效红光光催化
Metal-free brush-like 3D carbon nitride delivers efficient red-light-driven photocatalysis
摘要
Abstract
In this study,melamine and cyanuric acid were used as precursors to form supramolecular crystals via hydrogen-bond-assisted self-assembly followed by hydrothermal treatment.Subsequent high-temperature calcination yielded a novel brush-like three-dimensional carbon nitride.The brush-like 3D architecture was found to expose more accessible active sites,markedly accelerate electron transfer,and suppress the recombination of photogenerated charge carriers.The resulting superoxide(O2-·)and hydroxyl(·OH)radicals generated via electron reduction were identified as the key reactive species in the photocatalytic process.Moreover,the surface of the brush-like structure is enriched with nitrogen vacancies,which enhance the catalyst's ability to harvest visible light.The photocatalytic performance of the brush-like CNS-650 catalyst was evaluated for rhodamine B(RhB)degradation.Under red-light irradiation(660 nm),its degradation rate was 7.4 times higher than that of bulk CN.This work provides valuable insights into the design and application of efficient metal-free 3D photocatalysts.关键词
光催化/氮化碳/三维结构/红光Key words
photocatalysis/carbon nitride/three dimensional structure/red-light分类
化学化工引用本文复制引用
王鹏,韩燕玲,刘园园,芦鹏飞,李晓..非金属刷状三维氮化碳驱动高效红光光催化[J].燃料化学学报（中英文）,2026,54(3):92-104,13.基金项目
Supported by the National Natural Science Foundation of China(Grant 22578376,52374283)and the Natural Science Foundation of Jiangsu Province(Grant BK20240332). （Grant 22578376,52374283）
