Cu3P@CuO纳米片状催化剂用于氨硼烷的高效水解析氢
The Cu3P@CuO nanosheet catalyst used for the efficient hydrolysis of ammonia borane to produce hydrogen
摘要
Abstract
Ammonia borane(AB)is an excellent hydrogen storage material with low molecular weight and high hydrogen content.To fully unleash its value,the development of low-cost and highly active catalysts for AB hydrolysis hydrogen production is precisely the core path to promote the industrialization of AB hydrolysis hydrogen production technology.This paper used anhydrous copper chloride as raw material,and prepared copper oxide nanosheets(CuO NS)precursor by solvothermal method under alkaline conditions.Through low-temperature phosphating method,CuO NS was converted into Cu3P@CuO nanosheets(Cu3P@CuO NS).The microstructure and structural composition of Cu3P@CuO NS were characterized by SEM,TEM,AFM,XRD and XPS.The effects of as-prepared Cu3P@CuO NS for hydrogen evolution reaction(HER)from AB hydrolysis were investigated.Additionally,the hydrogen evolution rate and turnover frequency(TOF value)of Cu3P@CuO NS catalyzed AB hydrolysis were explored under different reaction conditions.The results showed that when the phosphating ratio was adjusted to m(CuO NS)/m(NaH2PO2)=1(m(CuO NS)=m(NaH2PO2)=0.1 g),Cu3P@CuO NS exhibited the optimal catalytic activity for AB hydrolysis.Cu3P@CuO NS exhibited a high turnover frequency(TOF),with a TOF value as high as 57.23 min-1 and an apparent activation energy of 44.31 kJ/mol.The hydrolysis of AB followed pseudo-first-order kinetics with respect to the catalyst dosage,while it exhibited pseudo-zero-order kinetics with respect to the AB dosage.The excellent performance exhibited by Cu3P@CuO NS could be attributed to the abundant active sites exposed by their nanosheet structure.Given the remarkably low cost of this catalyst,the Cu3P@CuO NS catalyst is highly anticipated to serve as a viable substitute for noble metal catalysts.It is poised to emerge as an ideal catalytic material for the hydrogen evolution reaction from AB,leveraging its cost-effectiveness and catalytic efficiency to address the challenges associated with high-cost noble metal-based systems.关键词
氢能/铜基催化剂/氨硼烷/纳米片Key words
hydrogen energy/copper-based catalyst/ammonia borane/nanosheet分类
化学化工引用本文复制引用
任文婷,陈雷云,沈佳蓓,谢婧,赵宇蝶,许立信,万超..Cu3P@CuO纳米片状催化剂用于氨硼烷的高效水解析氢[J].燃料化学学报（中英文）,2026,54(3):105-113,9.基金项目
Supported by the National Natural Science Foundation of China(22478001,22108238,U22A20408),Excellent Young Scholars Program of Natural Science Foundation Anhui Province(2408085Y005),Excellent Youth Scholars Program of Higher Education Institutions of Anhui Province(2024AH030008),the Open Fund of Shanghai Jiao Tong University Shaoxing Research Institute(JDSX2023014),China Postdoctoral Science Foundation(2019M662060,PC2022046,2020T130580),Open Research Funds of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(BM2012110),2024,2025 National Undergraduate Innovation and Entrepreneurship Training Program(202510360102,S202410360211),the State Key Laboratory of Clean Energy Utilization(ZJUCEU2024017),and the Open Project of Engineering Research Center of Biofilm Water Purification and Utilization Technology of Ministry of Education(BWPU2023KF06).国家自然科学基金(22478001,22108238,U22A20408),安徽省自然科学优秀青年项目(2408085Y005),安徽省高校优秀青年科研项目(2024AH030008),上海交通大学绍兴研究院开放课题(JDSX2023014),中国博士后科学基金(2019M662060,PC2022046,2020T130580),江苏省绿色催化材料与技术重点实验室(BM2012110),2024,2025年国家级大学生创新创业训练计划(202510360102,S202410360211),能源高效清洁利用全国重点实验室开放基金课题(ZJUCEU2024017)和生物膜法水质净化及利用技术教育部工程研究中心开放基金(BWPU2023KF06)资助 （22478001,22108238,U22A20408）
