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基于六水氯化钙的复合相变调湿材料的制备及热湿性能的研究

卢衍君 王军 曾织云 谢文敏 叶荣达

仲恺农业工程学院学报2026,Vol.39Issue(2):35-42,52,9.
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仲恺农业工程学院学报2026,Vol.39Issue(2):35-42,52,9.DOI:10.3969/j.issn.1674-5663.2026.02.005

基于六水氯化钙的复合相变调湿材料的制备及热湿性能的研究

Preparation and hygrothermal properties of composite phase change humidity control materials based on hexahydrate calcium chloride

卢衍君 1王军 1曾织云 1谢文敏 1叶荣达1

作者信息

  • 1. 仲恺农业工程学院 化学化工学院,广东 广州 510225
  • 折叠

摘要

Abstract

This paper investigates the preparation and hygrothermal properties of a composite phase change humidity control material.Using hexahydrate calcium chloride as the phase change material and expanded graphite as the carrier material,a composite phase change material was prepared through a porous adsorption method.This material was then combined with diatomite to produce a composite phase change humidity control material capable of regulating both temperature and humidity.The findings reveal that diatomite exhibits excellent humidity control capabilities,with a moisture buffer value of 3.81 g/m2·%RH,a specific surface area of 57.421 m2/g.The composite phase change material demonstrates a phase change temperature of 25.36℃and a latent heat of 90.68 J/g,alongside good thermal stability.By examining the thermal storage performance of the composite phase change material under varying humidity conditions,it was discovered that dry diatomite can slow the decline in the thermal properties of the composite phase change material,with the effect being more pronounced with increasing diatomite thickness.When the diatomite and composite phase change material were bonded using building structural adhesive,the thermal storage performance of the composite phase change humidity control material became unaffected by humidity.Applying the prepared composite phase change humidity control material in a small room model in the Guangzhou area demonstrated its effectiveness in reducing fluctuations in indoor temperature and humidity,thereby positively impacting the indoor thermal and humidity environment.

关键词

六水氯化钙/硅藻土/相变材料/调湿材料/热湿调控材料/建筑节能

Key words

hexahydrate calcium chloride/diatomite/phase change material/humidity control material/hygrothermal control material/building energy efficiency.

分类

通用工业技术

引用本文复制引用

卢衍君,王军,曾织云,谢文敏,叶荣达..基于六水氯化钙的复合相变调湿材料的制备及热湿性能的研究[J].仲恺农业工程学院学报,2026,39(2):35-42,52,9.

基金项目

国家自然科学基金项目(52006250). (52006250)

仲恺农业工程学院学报

1674-5663

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