材料工程2026，Vol.54Issue(3)：25-38,14.DOI:10.11868/j.issn.1001-4381.2025.000341
基于高缠结网络的功能软材料的设计和应用
Design and application of functional soft materials based on highly-entangled networks
摘要
Abstract
Highly entangled networks,as a novel design strategy for soft materials,effectively address the contradiction among strength,toughness,and fatigue resistance in traditional crosslinked materials by regulating the topological entanglement structure of molecular chains.This paper systematically reviews five strategies to construct highly entangled networks:high-concentration monomer polymerization,post-crosslinking of highly entangled chains,dual-network synergistic high entanglement of dual networks,macromolecular crosslinking high entanglement,and nanocomposite high entanglement.The molecular design principles,structural characteristics,and performance advantages of each strategy are analysed.In the field of functional applications,this review highlights the innovative applications of highly entangled materials in wear-resistant coatings,durable devices,adhesives,and intelligent actuators,demonstrating the excellent mechanical properties and unique functional characteristics endowed by highly entangled networks.Moreover,the challenges and future directions of highly entangled soft materials are discussed,emphasizing that multi-scale simulation technology,bionic adaptive design,and green manufacturing processes will be important research directions in this field.This review provides systematic theoretical guidance and technical reference for the design and application of functional soft materials with highly entangled networks.关键词
高缠结网络/力学性能/分子设计/软材料/功能开发Key words
high entangled networks/mechanical property/molecular design/soft materials/functional development分类
通用工业技术引用本文复制引用
高璐,吴文娟,赵传壮..基于高缠结网络的功能软材料的设计和应用[J].材料工程,2026,54(3):25-38,14.基金项目
宁波市青年科技领军人才(2024QL020) （2024QL020）
宁波大学力学+交叉学科拔尖创新青年基金项目资助(ZX2024000242) （ZX2024000242）
浙江省大学生科技创新活动计划(新苗人才计划2025R405A031) （新苗人才计划2025R405A031）
