发光学报2026，Vol.47Issue(2)：267-280,14.DOI:10.37188/CJL.20250207
具有AIE性质的金属有机笼的合成研究进展
Recent Advances in Synthesis of Metal-organic Cages with Aggregation-induced Emission Properties
摘要
Abstract
Metal-organic cages(MOCs)are discrete supramolecular architectures formed through the coordination-driven self-assembly of metal ions and organic ligands.These structures have garnered significant attention owing to their tunable geometries,diverse cavity configurations,and facile functionalization capabilities.In recent years,the rapid advancement of aggregation-induced emission(AIE)materials,along with their distinctive advantages in lumi-nescence mechanisms and functional design,has offered novel insights and opportunities for the development of inno-vative MOCs.This article provides an overview of the most recent advancements in the synthetic strategies for MOCs exhibiting AIE properties,with particular emphasis on the construction of AIE-active MOCs through the coordination-driven self-assembly of AIE chromophores,such as tetraphenylethylene(TPE)and carbazole,with center metals including Pt(Ⅱ),Zn(Ⅱ),Pd(Ⅱ),and Cd(Ⅱ).This class of compounds demonstrates not only superior optical properties but also extensive application potential across various advanced fields,including bioimaging,chemical and biological sensing,information storage and encryption,and light-harvesting systems.关键词
金属有机笼/聚集诱导发光/四苯基乙烯/超分子自组装Key words
metal-organic cages/aggregation-induced emission/tetraphenylethylene/supramolecular self-assembly分类
数理科学引用本文复制引用
韩欣,张吉富,肖健成,石林林,郝新奇..具有AIE性质的金属有机笼的合成研究进展[J].发光学报,2026,47(2):267-280,14.基金项目
湖北省教育厅科学研究计划青年人才项目(Q20233104) （Q20233104）
汉江师范学院基金项目(2024B11) （2024B11）
国家大学生创新创业训练计划项目(202410518017,202410518019) （202410518017,202410518019）
丹江口库区水生态环境与健康十堰市重点实验室(汉江师范学院)2025年度开放基金(DK22506)Supported by Scientific Research Project of Hubei Provincial Education Department(Q20233104) （汉江师范学院）
Foundation of Hanjiang Normal University(2024B11) （2024B11）
National College Students' Innovation and Entrepreneurship Training Program(202410518017,202410518019) （202410518017,202410518019）
2025 Annual Open Fund of the Key Laboratory of Danjiangkou Reservoir Area's Aquatic Eco-Environment and Health,Shiyan City(Hanjiang Normal University)(DK22506) （Hanjiang Normal University）
