火炸药学报2026，Vol.49Issue(2)：127-142,16.DOI:10.14077/j.issn.1007-7812.202507006
TKX-50单质及其混合炸药的研究进展
Research Progress on TKX-50 Monomer and Composite Explosives
摘要
Abstract
The recent advances in the novel high-energy-density material dihydroxylammonium 5,5'-bistetrazole-1,1'-diolate(TKX-50)for applications in monomer explosives and composite explosives were reviewed.By analyzing multidimensional re-search achievements in crystal structure,thermal behavior,synthesis methods,and composite systems,the unique ionic molec-ular configuration and synergistic hydrogen-bonding network mechanism of TKX-50 were elucidated,which confers the material with balanced characteristics of high density,low sensitivity,and superior detonation performance.Studies demonstrate that the synthesis process has evolved from traditional multi-step routes to one-pot methods and crystallization control strategies,significantly enhancing production efficiency and safety.In composite explosive systems,energy output optimization has been a-chieved through interface engineering and morphology control.The current research still confronts challenges in scalable pro-duction,component compatibility,and extreme environment adaptability.The future work should emphasize green synthesis processes,multi-scale simulations,and intelligent design to advance innovative applications of TKX-50 in advanced energetic materials.With 89 references were attached.关键词
应用化学/TKX-50/高能量密度材料/HEDMs/混合炸药/合成工艺/钝感材料/晶体工程Key words
applied chemistry/TKX-50/high-energy-density materials/HEDMs/composite explosives/synthesis processes/insensitive materials/crystal engineering分类
军事科技引用本文复制引用
陈明磊,尚凤琴,王俊峰,陈锟..TKX-50单质及其混合炸药的研究进展[J].火炸药学报,2026,49(2):127-142,16.基金项目
基础产品创新计划火炸药专项 （）
