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碳纤维上生长镍锰双金属氧化物电极材料的制备及电化学性能研究

崔金玲 赵海涛 秦宇

有色金属材料与工程2026,Vol.47Issue(1):9-16,8.
有色金属材料与工程2026,Vol.47Issue(1):9-16,8.DOI:10.13258/j.cnki.nmme.20250606002

碳纤维上生长镍锰双金属氧化物电极材料的制备及电化学性能研究

Preparation and electrochemical properties of nickel-manganese bimetallic oxide electrode materials grown on carbon fiber

崔金玲 1赵海涛 1秦宇2

作者信息

  • 1. 沈阳理工大学 材料科学与工程学院,沈阳 110159
  • 2. 沈阳恒久安泰环保与节能科技有限公司,沈阳 110027
  • 折叠

摘要

Abstract

Using nickel nitrate and manganese chloride as the main raw materials,nickel-manganese bimetallic oxide(Ni-MnO4)was grown on carbon fiber(CF)via the hydrothermal method.The effects of different molar ratios of Ni and Mn on the morphology,structure,and electrochemical properties of Ni-MnO4/CF were investigated.The structure,morphology,and electrochemical properties of the composite materials were characterized using X-ray diffractometer(XRD),scanning electron microscope(SEM),and an electrochemical workstation.The results indicate that adjusting the molar ratio of Ni and Mn,the morphology of the composite material can be well regulated and its electrochemical properties can be changed.With the increase of Ni element,the morphology of Ni-MnO4/CF gradually transforms from the stacked bud-like to thin sheet-like.When n(Ni)∶n(Mn)=2∶1,Ni-MnO4/CF exhibits relatively favorable electrochemical properties.When the current density increased from 1 A/g to 5 A/g,the specific capacitance of Ni-MnO4/CF decreased from 1 669 F/g to 1 015 F/g,and the specific capacitance retention rate is 60.8%.

关键词

双金属氧化物/碳纤维/水热法/电化学性能

Key words

bimetallic oxide/carbon fiber/hydrothermal method/electrochemical properties

分类

通用工业技术

引用本文复制引用

崔金玲,赵海涛,秦宇..碳纤维上生长镍锰双金属氧化物电极材料的制备及电化学性能研究[J].有色金属材料与工程,2026,47(1):9-16,8.

基金项目

沈阳市科技局资助项目(22-322-3-18) (22-322-3-18)

有色金属材料与工程

2096-2983

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