低碳化学与化工2026，Vol.51Issue(3)：41-52,12.DOI:10.12434/j.issn.2097-2547.20250123
醇氧化反应中非均相催化剂的界面调控研究进展
Research advances in interface modulation of heterogeneous catalysts for alcohol oxidation reactions
摘要
Abstract
Carbonyl compounds are extensively utilized in pharmaceutical and fine chemical industries.The selective oxidation of alcohols serves as an important pathway for synthesizing carbonyl compounds.However,conventional thermal catalytic methods suffer from harsh reaction conditions,low target product selectivities and environmental concerns.Heterogeneous catalysts have demonstrated unique advantages in high-efficiency selective oxidation of alcohols,and their catalytic performances depend on geometric and electronic configurations of the catalyst.Interface engineering enables precise optimization of alcohol adsorption and activation processes through modulation of interfacial active sites.The regulatory mechanisms and strategies of interface engineering in thermocatalytic heterogeneous alcohol oxidation reactions were reviewed.The mechanisms of interfacial modulation of non-homogeneous catalysts by electronic and geometrical effects were discussed and the interface-based modulation methodologies were analyzed.In addition,a brief discussion of the impact of artificial intelligence-assisted approaches on catalyst design was provided and the future development direction of designing interfacial active sites in alcohol oxidation reactions via interface engineering was prospected.关键词
界面工程/醇氧化/热催化/调控机制/非均相催化剂Key words
interfacial engineering/alcohol oxidation/thermocatalysis/modulation mechanisms/heterogeneous catalysts分类
化学化工引用本文复制引用
孟同欣,武世平,赵金仙,樊惠玲,杨超..醇氧化反应中非均相催化剂的界面调控研究进展[J].低碳化学与化工,2026,51(3):41-52,12.基金项目
国家自然科学基金青年基金(22208233) （22208233）
国家自然科学基金(22078223). （22078223）
