常州大学学报（自然科学版）2026，Vol.38Issue(2)：20-27,8.DOI:10.3969/j.issn.2095-0411.2026.02.003
可见光诱导钴催化烯丙基叠氮类化合物的合成
Photo-induced cobalt-catalyzed synthesis of allylic azides
摘要
Abstract
Using 1,3-dienes as substrates and azidetrimethylsilanes as nucleophilic azide sources,a novel photo-induced cobalt-catalyzed regioselective 1,2-hydroazidation of 1,3-dienes were reported.A series of allyl azides were synthesized in moderate to good yields.The use of 2,4,6-trimethylpyri-dine trifluoromethanesulfonate as hydrogen source obviated the need for stoichiometric oxidant or re-ductant.Mechanistic studies have shown that this reaction involves a catalytic cycle from Co(Ⅰ)to Co(Ⅳ).The reaction conditions were mild and easy to operate,and the products were correctly iden-tified by 1H NMR,13C NMR and high-resolution mass spectrometry.关键词
可见光催化/钴催化/氢叠氮化/烯丙基叠氮Key words
photo catalysis/cobalt catalysis/hydroazidation/allylic azides分类
化学化工引用本文复制引用
朱啻凡,伏慧楠,范子瑞,黄本清..可见光诱导钴催化烯丙基叠氮类化合物的合成[J].常州大学学报（自然科学版）,2026,38(2):20-27,8.基金项目
江苏省高等学校基础科学(自然科学)研究面上资助项目(23KJB530001) （自然科学）
常州大学科研启动经费资助项目(ZMF22020012). （ZMF22020012）
