常州大学学报（自然科学版）2026，Vol.38Issue(2)：28-35,8.DOI:10.3969/j.issn.2095-0411.2026.02.004
热活化过硫酸盐降解废水中的吉米沙星
Degradation of gemifloxacin in wastewater by heat-activated persulfate oxidation
摘要
Abstract
To assess the feasibility of heat-activated Persulfate(PS)oxidation for the degradation of Gemifloxacin(GMX)in wastewater,the kinetics of GMX degradation and activation energy were in-vestigated through batch experiments.Various reaction conditions and the influence of coexisting wa-ter matrices on GMX degradation performance were examined.The results indicated that increasing temperature and persulfate concentration significantly enhanced GMX degradation,which followed a first-order kinetic model with an activation energy of 104.22 kJ/mol.Under acidic and neutral condi-tions,sulfate radicals(·SO-4)were the primary contributors to GMX degradation,while hydroxyl radicals(·OH)contributed equally to·SO-4 under strong alkaline conditions that was associated with a decrease in the rate of GMX degradation.Chloride ions promoted the GMX degradation,while bicarbonate and fulvic acid inhibited it.Despite a mineralization rate of only 30.6%for GMX,the in-termediate products generated in the reaction did not exhibit microbial toxicity.关键词
热活化过硫酸盐/吉米沙星/动力学/影响因素Key words
heat-activated persulfate/gemifloxacin/kinetics/influence factor分类
资源环境引用本文复制引用
王继鹏,李健康,陈海群..热活化过硫酸盐降解废水中的吉米沙星[J].常州大学学报（自然科学版）,2026,38(2):28-35,8.基金项目
国家自然科学基金资助项目(52300076). （52300076）
