塑料科技2026，Vol.54Issue(2)：34-38,5.DOI:10.15925/j.cnki.issn1005-3360.2026.02.006
本征阻燃聚氨酯弹性体制备及其性能研究
Preparation and Performance Study of Intrinsically Flame Retardant Polyurethane Elastomer
摘要
Abstract
In the study,a highly efficient reactive flame retardant polyether polyol was synthesized by one-pot method using a commercial bimetallic cyanide(DMC)catalyst.The effects of design molecular weight and other parameters on the polymerization activity of flame retardant polyether polyols were studied.The intrinsic flame retardant polyurethane elastomer(FR-PU)was further prepared by using flame retardant polyether polyol as flame retardant carrier.Unlike traditional flame retardants that reduce the mechanical properties of the material,the mechanical properties of the intrinsic flame retardant polyurethane elastomer prepared by the reactive flame retardant polyether were not significantly reduced.The thermal stability and flame retardant mechanism of FR-PU were studied by thermogravimetric analysis and cone calorimeter,respectively.The results showed that the heat release rate(HRR)and total heat release(THR)of polyurethane elastomer both decreased by about 40%when the addition mass fraction of flame retardant polyether in the total formula of polyether increased to 20%,and the gas phase and condensed phase flame retardant worked together.The method provides a new strategy for the development of flame retardant polyurethane materials.关键词
一锅法/聚氨酯/阻燃性/聚醚多元醇Key words
One-pot method/Polyurethane/Flame retardancy/Polyether polyol分类
化学化工引用本文复制引用
张晓菲,徐佳宝,何颖,万晓晗,吴会咏,李文泽,张潇飒..本征阻燃聚氨酯弹性体制备及其性能研究[J].塑料科技,2026,54(2):34-38,5.基金项目
辽宁省教育厅高校基本科研项目(LJ212410149041) （LJ212410149041）
辽宁省教育厅面上项目(LJKMZ20220790) （LJKMZ20220790）
辽宁省科技厅应用基础研究计划项目(2023JH2/101300231) （2023JH2/101300231）
