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磷掺杂氮化碳管的制备及其光催化制氢性能

周正 李晶 阿蕊滋 杨亮糯 李国良 李明 顾振华

云南师范大学学报(自然科学版)2026,Vol.46Issue(1):74-78,5.
云南师范大学学报(自然科学版)2026,Vol.46Issue(1):74-78,5.DOI:10.7699/j.ynnu.ns-2026-12

磷掺杂氮化碳管的制备及其光催化制氢性能

Synthesis of Phosphorus-doped Carbon Nitride Nanotubes and Their Photocatalytic Hydrogen Evolution Performance

周正 1李晶 1阿蕊滋 1杨亮糯 1李国良 1李明 1顾振华1

作者信息

  • 1. 云南师范大学能源与环境科学学院,云南 昆明 650500
  • 折叠

摘要

Abstract

Nitrogen-carbon tubes were successfully synthesized via a combined hydrothermal and ther-mal polymerization method,followed by phosphorus doping modification.The test results indicate that phosphorus-doped nitrogen-carbon nanotubes exhibit significantly enhanced visible light absorption ca-pacity,thereby improving solar energy utilization efficiency.Simultaneously,phosphorus doping facili-tates the migration and separation of photogenerated charge carriers in the nitrogen-carbon nanotubes.The phosphorus-doped nitrogen-carbon nanotubes demonstrate excellent photocatalytic hydrogen evo-lution activity,with a hydrogen production rate reaching 3 352.3 μmol·h-1·g-1,which is approxi-mately 2.4 times and 11.6 times higher than that of undoped phosphorus nitrogen-carbon nanotubes and bulk carbon nitride,respectively.

关键词

光催化/磷掺杂/光催化制氢/管状氮化碳/形貌调控

Key words

Photocatalysis/Phosphorus doping/Photocatalytic hydrogen production/Tubular carbon ni-tride/Morphology control

分类

化学化工

引用本文复制引用

周正,李晶,阿蕊滋,杨亮糯,李国良,李明,顾振华..磷掺杂氮化碳管的制备及其光催化制氢性能[J].云南师范大学学报(自然科学版),2026,46(1):74-78,5.

基金项目

云南省"兴滇英才支持计划"青年人才资助项目(XDYC-QNRC-202-0060). (XDYC-QNRC-202-0060)

云南师范大学学报(自然科学版)

1007-9793

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