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油田VOCs浓度分布特征及臭氧生成潜势

隆嘉欣 王颖 王凌匀 何战友 任小荣 赵天一 魏瑞瑞 李伟

环境工程学报2026,Vol.20Issue(2):485-497,13.
环境工程学报2026,Vol.20Issue(2):485-497,13.DOI:10.12030/j.cjee.202505042

油田VOCs浓度分布特征及臭氧生成潜势

Characteristics of VOC concentrations and their ozone formation potential in oilfields

隆嘉欣 1王颖 2王凌匀 3何战友 4任小荣 4赵天一 1魏瑞瑞 1李伟1

作者信息

  • 1. 兰州大学大气科学学院,兰州 730000
  • 2. 兰州大学大气科学学院,兰州 730000||兰州大学半干旱气候变化教育部重点实验室,兰州 730000
  • 3. 中国石油长庆油田分公司质量健康安全环保部,西安 710018
  • 4. 中国石油长庆油田分公司油气工艺研究院,西安 710018
  • 折叠

摘要

Abstract

To address ozone(O3)pollution caused by fugitive volatile organic compound(VOC)emissions from typical process stations in the oilfield extraction industry,VOC concentrations from key emission sources were systematically quantified and their concentration distribution characteristics were statistically analyzed.The ozone formation potential(OFP)of individual components was then calculated using the Maximum Incremental Reactivity(MIR)and Propylene Equivalent Concentration(PEC)methods to inform strategies for reducing oil loss and controlling O3.The results showed that among various emission sources,VOCs from storage tank emissions exhibited the widest concentration range and the highest median(55 750 mg·m-3),followed by fugitive emissions from the produced water treatment process(median:909 mg·m-3).Elevated leak concentrations from dynamic and static seals were primarily found at well fields and pressurization points,where flanges and valves were the dominant leak types.Compositional analysis revealed that alkanes were the predominant group in VOCs from both storage tank volatile losses and the produced water treatment emissions,yet the latter exhibited significantly higher mass concentrations of aldehydes,ketones,and alkenes.Consequently,the OFP per unit VOC concentration(μg·m-3)from the produced water treatment process was approximately 1.5 times that from storage tank emissions.This study demonstrates that implementing stringent controls on storage tank VOC emissions and enhancing environmental regulation of fugitive emissions from the produced water treatment process are critical measures for reducing total VOC emissions and mitigating O3 formation potential in the oilfield extraction industry.

关键词

油田/挥发性有机物/最大增量反应活性/等效丙烯浓度/臭氧生成潜势

Key words

oilfield/volatile organic compounds/maximum incremental reactivity/propylene equivalent concentration/ozone formation potential

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资源环境

引用本文复制引用

隆嘉欣,王颖,王凌匀,何战友,任小荣,赵天一,魏瑞瑞,李伟..油田VOCs浓度分布特征及臭氧生成潜势[J].环境工程学报,2026,20(2):485-497,13.

环境工程学报

1673-9108

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