高压物理学报2026，Vol.40Issue(4)：35-42,8.DOI:10.11858/gywlxb.20251268
三元氢化物(Th,Y)H10的合成及超导电性
Synthesis and Superconductivity of the Ternary Hydrides(Th,Y)H10
摘要
Abstract
Recent achieved superconductivity near room temperature,especially in hydrogen-based super-conductors under high pressure,have attracted broad interest.However,most systems with high superconducting critical temperature(Tc)are only stable under extremely high pressures,which limits their practical applicability.This study proposes the possibility of obtaining high-Tc superconductors at moderate pressures within the ternary Th-Y-H system.The synthesis was carried out using Th,YH3,and NH3BH3 as precursors under high pressure and high temperature,applied by diamond anvil cells combined with in-situ laser heating technology.Combining with the synchrotron X-ray diffraction(XRD)measurements and theoretical studies,the main product was identified as Fm3m(Th,Y)H10,with Y accounting for approximately 10%-15%.Electrical transport measurements reveal that its Tc increases by approximately 10%,compared to ThH10 under similar pressure.At 144 GPa,the sample has a maximum Tc of 184 K,which remains at 170 K when decompressed to 100 GPa—approaching the highest level known for hydrides at this pressure.Measurements under an applied magnetic field further verify the superconductivity,with upper critical fields estimated at 52 and 39 T based on the WHH and GL models,respectively.These results indicate that the ternary Th-Y-H superconducting system is an outstanding candidate for high-Tc superconductors,and the crystal stability and electronic properties can be effectively controlled by reasonably introducing new element into the binary system.This work provides new insights and experimental evidences for exploring high-Tc superconducting hydrides under moderate or even low pressures.关键词
三元氢化物/超导电性/Th-Y-H体系/高压/超导转变温度Key words
ternary hydrides/superconductivity/Th-Y-H system/high pressure/superconducting critical temperature分类
数理科学引用本文复制引用
宋晓旭,郝晓宽,牛景雨,高国英,田永君..三元氢化物(Th,Y)H10的合成及超导电性[J].高压物理学报,2026,40(4):35-42,8.基金项目
国家自然科学基金(52372261,52288102) （52372261,52288102）
河北省自然科学基金(E2024203045) （E2024203045）
河北省科技计划项目(225A1102D) （225A1102D）
国家重点研发计划(2022YFA1402300) （2022YFA1402300）
