高压物理学报2026，Vol.40Issue(4)：52-59,8.DOI:10.11858/gywlxb.20251216
金属氢配体化合物:环境压力下通往超导金属氢的潜在道路
Metallic Hydrogen Ligand Compounds:A Potential Route to Superconducting Metallic Hydrogen at Ambient Pressure
摘要
Abstract
Metallic hydrogen,with its properties including room-temperature superconductivity and quantum fluidity,is known as the holy grail of high-pressure physics.However,since atomic metallic hydrogen requires pressures about 500 GPa,it has not been realized in experiments since its conception in 1935.To take advantage of properties the properties of metallic hydrogen in the future,it will be crucial to obtain it at ambient pressure.Current approaches to obtaining metallic hydrogen at low pressures rely on the"chemical precompression"in hydrides to induce metallization of hydrogen at low pressures,essentially identifying superconducting hydrides that can host the properties of metallic hydrogen.However,these superconducting hydrides currently lack distinct structural features,complicating the search for metallic hydrogen hosts.Here,we identify metallic hydrogen ligand compounds with hydrogen as the ligands as potential hosts for properties of metallic hydrogen at low pressures.The metallization of the non-bonding orbitals of the hydrogen ligands is a key criterion for determining whether a metallic hydrogen ligand compound can host metallic hydrogen properties.This article summarizes the main behaviors of hydrogen at ambient pressure,focusing on hydrogen ligand compounds at ambient pressure.Then,using a simple model of a one-dimensional hydrogen atom chain,we analyzed the causes of non-bonding orbital metallization and the physical picture of reduced stability pressure.The orbital characteristics of metallic hydrogen ligand compounds are then analyzed,highlighting their rules of superconductivity,topological properties,and the electronic structure that enable metallization.The analysis of metallic hydrogen ligand compounds presented in this article not only provides important structural information for future exploration of metal hydride superconductors but also provides an important theoretical foundation for realizing the properties of metallic hydrogen at ambient pressure.关键词
金属氢/超导氢化物/电子结构/化学预压缩Key words
metallic hydrogen/superconducting hydrides/electronic structure/chemical precompression分类
数理科学引用本文复制引用
张子涵,段德芳,崔田..金属氢配体化合物:环境压力下通往超导金属氢的潜在道路[J].高压物理学报,2026,40(4):52-59,8.基金项目
国家重点研发计划(2022YFA1402304,2023YFA1406200) （2022YFA1402304,2023YFA1406200）
国家自然科学基金(12122405,122741695) （12122405,122741695）
中央高校基本科研业务费专项资金 （）
