应用化学2026，Vol.43Issue(3)：360-372,中插1-中插4,17.DOI:10.19894/j.issn.1000-0518.250226
合金元素(Sn、Sb、Si、Mn)对Al-Ga-In-M合金阳极电化学性能影响
Effects of Alloy Elements(Sn,Sb,Si,Mn)on the Electrochemical Performance of Al-Ga-In-M Anode for the Seawater Oxygen-Dissolved Battery
摘要
Abstract
The Al-Ga-In-M quaternary aluminum alloy anode was obtained by modifying the Al-Ga-In aluminum alloy with alloy elements of Sn,Sb,Si and Mn.The properties of Al-Ga-In-M quaternary aluminum alloy were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),electrochemical experiments,and battery discharge tests.The results show that Sn and Sb can improve the electrochemical activity of Al-Ga-In aluminum alloy.Furthermore,Sn displays the most significant increase for the aluminum anode based on the"dissolution and redeposition"mechanism,but serious local corrosion occurs,resulting in a high self-corrosion rate.On the other hand,Si and Mn reduce the electrochemical activity of Al-Ga-In aluminum alloy and show good self-corrosion resistance.When combining the anode with 20％Pt-C composite cathode,Al-Ga-In-Sn alloy has the highest discharge voltage(1.5 V at 0.5 mA/cm2 constant current density),Al-Ga-In-Si alloy anode exhibits excellent discharge capacity(2941 A·h/kg),and Al-Ga-In-Sb alloy anodes have the highest energy density(1447.4 Wh/kg).关键词
Al-Ga-In-M(M=Sn、Sb、Si、Mn)阳极/合金元素改性/海水溶解氧电池/电化学性能Key words
Al-Ga-In-M(M=Sn、Sb、Si、Mn)anode/Alloy element modification/Seawater oxygen-dissolved battery/Electrochemical performance分类
化学化工引用本文复制引用
刘爽,段体岗,马力,李若灿,吴厚燃,张海兵,李祯..合金元素(Sn、Sb、Si、Mn)对Al-Ga-In-M合金阳极电化学性能影响[J].应用化学,2026,43(3):360-372,中插1-中插4,17.基金项目
国家重点研发计划(No.2022YFB3808800)资助 Supported by the National Key R&D Program of China(No.2022YFB3808800) （No.2022YFB3808800）
