电源技术2026，Vol.50Issue(4)：707-714,8.DOI:10.3969/j.issn.1002-087X.2026.04.015
氧化锡锑/二氧化钛/木棉碳改性凝胶电解质的制备及性能
Preparation and properties of antimony-doped tin oxide/titanium dioxide/kapok carbon modified gel electrolyte
摘要
Abstract
Polyvinyl alcohol(PVA)was used as the matrix of hydrogel electrolyte.The conductivity of the hydrogel electrolyte was improved by adding antimony-doped tin oxide(ATO).Nanoparticulate titanium dioxide(TiO2)and kapok carbon(KC)were introduced to interact with the hydroxyl groups in PVA,forming a three-dimensional channel network,which improved the structure of the hydrogel electrolyte and enhanced its ion transport capacity and electrochemical stability.The test results show that the ionic conductivity of the PVA/ATO/TiO₂/KC hydrogel electrolyte is 1.61 mS/cm,with a corrosion potential(Ecorr)of 0.517 V and a corrosion current(Icorr)of 0.003 42 mA.For the correspond-ing full cell under 1 C condition,the initial specific capacity is 148.3 mAh/g,and the capacity reten-tion rate after 300 cycles is 90.7%.In addition,zinc deposition on the anode is relatively uniform,which alleviates the dendrite growth.The modified hydrogel electrolyte significantly improves the cycle stability and electrochemical reversibility of the battery.关键词
锌离子电池/聚乙烯醇水凝胶电解质/氧化锡锑/二氧化钛/木棉碳Key words
zinc-ion battery/polyvinyl alcohol hydrogel electrolyte/antimony-doped tin oxide/tita-nium dioxide/kapok carbon分类
信息技术与安全科学引用本文复制引用
蔡敏,吴春燕,黄莹莹,王胜杰,韦宗辰..氧化锡锑/二氧化钛/木棉碳改性凝胶电解质的制备及性能[J].电源技术,2026,50(4):707-714,8.基金项目
2024年崇左市科技"尖锋"专项项目(崇科20241205) （崇科20241205）
2024年崇左市科技"尖锋"专项项目(崇科20231212) （崇科20231212）
2025年广西自治区级大学生创新创业训练计划项目(S202510604134) （S202510604134）
广西民族师范学院校级科研项目(2021BS003) （2021BS003）
