辐射研究与辐射工艺学报2026，Vol.44Issue(2)：1-16,16.DOI:10.11889/j.1000-3436.2026-0019
电离辐射诱导金属有机框架的合成和功能化研究进展
Research progress on synthesis and functionalization of metal-organic frameworks induced by ionizing radiation
摘要
Abstract
Metal-organic frameworks(MOFs)are mainly synthesized via hydrothermal/solvothermal methods,which involve high temperature,high pressure,long time,and high energy consumption in the reaction process.Although traditionally synthesized MOFs exhibit high crystallinity,their pore structures are monotonous and lack specific functional groups,severely limiting the enhancement of intrinsic properties and the expansion of application domains.Consequently,the efficient and green synthesis of high-performance functional MOFs remains challenging.Ionizing radiation technology plays a key role in the efficient synthesis and functionalization of crystalline porous materials,leveraging its unique activation and etching effects.This review summarizes recent research on the ionizing radiation-based synthesis and functionalization of MOFs,covering in-situ gamma ray/electron beam radiation-assisted strategies for constructing defect-rich MOFs and heterostructures,as well as post-radiation modification methods for preparing functionalized MOFs and their subsequent applications.关键词
金属有机框架/电离辐射技术/辐射合成/辐射改性Key words
Metal-organic frameworks/Ionizing radiation technology/Radiation synthesis/Radiation modification分类
能源科技引用本文复制引用
陈俊畅,李春杨,毛选之,张明星,王殳凹..电离辐射诱导金属有机框架的合成和功能化研究进展[J].辐射研究与辐射工艺学报,2026,44(2):1-16,16.基金项目
国家自然科学基金(22425061,22227809,12305397)、江苏省自然科学基金(BK20230511,BK20250782)、国家博士后创新人才计划(BX20240247)、苏州市基础研究项目(SJC2023001)、中国博士后科学基金(2024M762298)和新基石科学基金会所设立的科学探索奖 Supported by National Natural Science Foundation of China(22425061,22227809,12305397),Natural Science Foundation of Jiangsu Province(BK20230511,BK20250782),the fellowship of China National Post-doctoral Program for Innovative Talents(BX20240247),Suzhou Fundamental Research Project(SJC2023001),China National Postdoctoral Science Foundation(2024M762298),and the New Cornerstone Science Foundation through the XPLORER PRIZE （22425061,22227809,12305397）
