辐射研究与辐射工艺学报2026，Vol.44Issue(2)：29-44,16.DOI:10.11889/j.1000-3436.2026-0023
辐射技术诱导的金属有机框架合成、缺陷调控及表面功能化研究进展
Research progress on radiation-induced metal-organic framework synthesis,defect regulation,and surface functionalization
摘要
Abstract
Metal-organic framework(MOF)is a porous material formed by the self-assembly of metal nodes and organic ligands,featuring a high specific surface area and tunable structure,and it is widely used in catalysis,separation,and other fields.However,traditional preparation and modification methods face challenges such as high energy consumption,long processing times,and reagent residues.In recent years,with the rise of green synthesis concepts and the integration of nuclear technology into materials science,ionizing radiation technologies represented by gamma rays and electron beams have gradually emerged as a promising approach for MOF preparation and modification.This is due to their unique energy transfer mechanisms,reactions that do not require high temperatures or pressures,and the'clean'characteristic of avoiding additional chemical reagents.This review aims to systematically summarize and analyze the recent frontiers of radiation technology in the field of MOF research,focusing on its applications in radiation-induced synthesis,defect regulation and surface radiation-induced graft functionalization.It details the mechanisms,technical advantages,challenges faced,and provides an outlook on future development trends.关键词
金属有机框架/电离辐射技术/缺陷调控/表面功能化Key words
Metal-organic framework/Ionizing radiation technology/Defect regulation/Surface functionalization分类
能源科技引用本文复制引用
胡一诺,王维,于荣荣,Siddique Amna,李文丽,赵晓蒙,邵瑞琪,徐志伟..辐射技术诱导的金属有机框架合成、缺陷调控及表面功能化研究进展[J].辐射研究与辐射工艺学报,2026,44(2):29-44,16.基金项目
国家自然科学基金(12575371) Supported by National Natural Science Foundation of China(12575371) （12575371）
