高等学校化学学报2026，Vol.47Issue(5)：179-195,17.DOI:10.7503/cjcu20250411
含Si,P,B的非传统超支化发光聚合物研究进展
Recent Progress on Unconventional Hyperbranched Luminescent Polymers Containing Si,P and B
摘要
Abstract
This review summarizes recent advances in unconventional hyperbranched luminescent polymers containing Si,P,and B.These luminescent polymers form three-dimensional hyperbranched topological structures through organic-inorganic hybrid units such as Si-O-C,P-O-C,and B-O-C.Internally enriched with heteroatoms bearing lone pairs(e.g.,O,N,S),these heteroatoms spontaneously form clusteroluminogens through spatial n/π interactions,multiple hydrogen-bond networks and nonmetallic coordination bonds.Exhibiting excellent biocompatibility,these luminescent materials demonstrate significant application potential in fields such as drug-controlled-release visualization,cellular bioimaging,and advanced information encryption.We focus on discussing the luminescence mechanism and structure-property relationships of this luminescent material,while identifying current challenges and future research directions.关键词
聚集诱导发光/聚合物/簇发光/超支化聚硅氧烷Key words
Aggregation-induced emission/Polymer/Clusteroluminescence/Hyperbranched polysiloxane分类
化学化工引用本文复制引用
吴锐,李政,李琪,石佳俊,赵艳,冯维旭,颜红侠..含Si,P,B的非传统超支化发光聚合物研究进展[J].高等学校化学学报,2026,47(5):179-195,17.基金项目
国家自然科学基金(批准号:22175143,22575194)资助. Supported by the National Natural Science Foundation of China(Nos.22175143,22575194). （批准号:22175143,22575194）
