高等学校化学学报2026，Vol.47Issue(5)：209-224,16.DOI:10.7503/cjcu20260130
主客体作用力构建的聚集诱导发光型超分子聚合物的合成与应用研究
Synthesis and Application of Aggregation-induced Emission Supramolecular Polymers Constructed by Host-guest Interaction
摘要
Abstract
As the core field of supramolecular chemistry,host-guest chemistry leverages the dynamic and reversible non-covalent interactions between host and guest molecules to endow systems with unique stimuli-responsiveness,demonstrating potential in the construction of intelligent materials.Incorporating aggregation-induced emission(AIE)fluorophores to functionalize supramolecular monomers serves as a pivotal strategy for equipping supramolecular polymer systems with optical sensing and bioimaging capabilities.In this work,we systematically review the primary synthetic strategies for AIE-active supramolecular polymers driven by host-guest interactions and elaborate on the assembly systems constructed from five categories of classical macrocyclic hosts alongside their current applications.Furthermore,the challenges encountered in the precision preparation,in-situ characterization,and practical implementation of these polymers are discussed in depth.关键词
聚集诱导发光/主客体相互作用/超分子聚合物/刺激响应性Key words
Aggregation-induced emission(AIE)/Host-guest interaction/Supramolecular polymer/Stimuli-respon-siveness分类
化学化工引用本文复制引用
潘晶珂,齐馨,张露露,王贝贝,吕超..主客体作用力构建的聚集诱导发光型超分子聚合物的合成与应用研究[J].高等学校化学学报,2026,47(5):209-224,16.基金项目
国家自然科学基金(批准号:22534007,22304164,U22A20397)资助. Supported by the National Natural Science Foundation of China(Nos.22534007,22304164,U22A20397). （批准号:22534007,22304164,U22A20397）
