硅酸盐通报2026，Vol.45Issue(3)：946-960,15.DOI:10.16552/j.cnki.issn1001-1625.2025.1105
氧化铌对玻璃和微晶玻璃结构、光学性能和电学性能的影响
Impact of Niobium Oxide on Structure,Optical Performance and Electrical Performance of Glass and Glass-Ceramics
摘要
Abstract
Niobium oxide(Nb2O5),as a functional oxide with unique structure and excellent properties,shows great potential in promoting the development of new-generation high-performance glass and glass-ceramics.This paper systematically reviews the recent research progress in niobium-containing glass and glass-ceramics.Firstly,the coordination state and network role evolution of Nb5+in different glass matrices(such as silicate,tellurite and phosphate)were deeply analyzed,and the structure-activity relationship of field strength matching principle and charge compensation mechanism on thermal stability and chemical durability is revealed.Secondly,the synergistic regulation mechanism of Nb5+in improving refractive index,enhancing third-order nonlinear optical response and optimizing rare earth ion luminescence is reviewed,and the tailoring effect of Nb-O-RE bonding topology on local crystal field is revealed.Furthermore,the crystallization kinetics based on the heredity of glassy structure and the revolutionary breakthrough of femtosecond laser-induced crystallization technology in realizing three-dimensional patterning and submicron precision of LiNbO3 ferroelectric crystal phase are discussed in detail,and the physical mechanism of periodic self-organization driven by laser-induced Marangoni convection is clarified.Finally,the future development trends of niobium-containing glass and glass ceramics in the fields of cross-scale computing design,new material system exploration and multi-functional integrated devices are prospected.The purpose of this paper is to provide a reference for the in-depth research and innovative application of niobium-containing glass and glass ceramics.关键词
氧化铌/玻璃/微晶玻璃/非线性光学/激光诱导结晶/铁电性Key words
niobium oxide/glass/glass-ceramics/nonlinear optics/laser-induced crystallization/ferroelectricity分类
化学化工引用本文复制引用
马俊艺,芦建超,王宏妮,师彦春,郭爱民,郑秋菊..氧化铌对玻璃和微晶玻璃结构、光学性能和电学性能的影响[J].硅酸盐通报,2026,45(3):946-960,15.基金项目
中信铌钢发展奖励基金 （）
