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基于斜坡实验的高固含量推进剂药浆流变行为研究

杨大为 赵文爽 郭彦强 宗原 周涛

固体火箭技术2026,Vol.49Issue(2):315-324,10.
固体火箭技术2026,Vol.49Issue(2):315-324,10.DOI:10.7673/j.issn.1006-2793.2026.02.017

基于斜坡实验的高固含量推进剂药浆流变行为研究

Rheological behavior of high solid content propellant based on slope experiments

杨大为 1赵文爽 1郭彦强 1宗原 2周涛1

作者信息

  • 1. 西安航天化学动力有限公司,西安 710025
  • 2. 华东理工大学,上海 200237
  • 折叠

摘要

Abstract

The solid content in hydroxyl-terminated polybutadiene(HTPB)is usually extremely high(ϕ≥0.5),and there exists complex interactions between particles and binders as well as among particles.Its rheological properties are significantly different from those of solid-liquid systems with low and medium contents.In the present work,an inclined-plane rheometer was built to suit the specific properties of HTPB systems.Propellant substitutes with high-solid suspensions(ϕ=0.365~0.513)were prepared using high-viscosity hydroxyl-terminated polybutadiene(HTPB)as the binder and acrylate-styrene-acrylonitrile(ASA)particles as solids.A laser displacement sensor was used to measure the liquid-film thickness and surface velocity of the flows on the slope,and the explicit expressions for the power-law index n and consistency coefficient K were derived from the power-law model to establish the constitutive equation.The results show that n falls from 0.893 to 0.432 and K rises from 153.6 Pa·sn to 670.9 Pa·sn as ϕ increases from 0.365 to 0.513.These phenomena reflect strong shear-thinning behavior,and these model parameters,i.e.n and K,exhibit exponential dependence on solid content ϕ.Empirical correlations for n and K as functions of ϕ are now available with a prediction error below 10%.The method provides a simple and reliable means of characterizing high-solid HTPB propellants and delivers the essential physical property data required for equipment design and process optimization.

关键词

HTPB推进剂/高固含量/斜坡流动/非牛顿流变行为/流变本构方程

Key words

HTPB propellant/high solid content/inclined-plane flow/non-Newtonian rheological behavior/rheological constitutive equation

分类

航空航天

引用本文复制引用

杨大为,赵文爽,郭彦强,宗原,周涛..基于斜坡实验的高固含量推进剂药浆流变行为研究[J].固体火箭技术,2026,49(2):315-324,10.

固体火箭技术

1006-2793

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