海洋科学2025,Vol.49Issue(12):92-103,12.DOI:10.11759/hykx20251011001
海洋有机磷酸酯及其生物富集研究进展
Review of marine organophosphate esters and their bioac-cumulation
摘要
Abstract
Organophosphate esters(OPEs)are widely used as flame retardants,plasticizers,and lubricants,yet at-tract considerable attention because of their high toxicity,environmental persistence,and bioaccumulation potential.This paper analyses the distribution,bioaccumulation,and biomagnification characteristics of OPEs in marine en-vironments,along with the factors that influence these characteristics,based on domestic and international research data.The findings summarize that the primary sources of OPE contamination of the marine environment are river-ine inputs and atmospheric deposition.Benthic organisms exhibited greater bioaccumulation potential than pelagic species.High-trophic-level organisms across the open ocean and polar regions contain elevated OPE concentrations.Novel organophosphate esters and organophosphate diesters were detected in certain aquatic organisms.OPE bio-accumulation potential correlated positively with the octanol-water partition coefficient.OPE levels differ between visceral and muscular tissues,as metabolic capacities also vary.Fat content may also influence bioaccumulation,though this remains controversial.Elevated water temperatures accelerate OPE metabolism,whereas winter and high-latitude waters favor bioaccumulation.This study analyzes and summarizes the factors influencing the char-acteristics of OPE bioaccumulation and transfer among marine organisms,providing scientific support for future risk management and standardization of OPEs in marine ecological systems.关键词
有机磷酸酯/分布特征/生物富集/影响因素Key words
organophosphate esters/distribution characteristics/bioaccumulation/influencing factors分类
海洋科学引用本文复制引用
王皓,程萌,杨萌,朱梓铭,刘若曦,李明燃,孙茂淇,姚德生,张玉凤..海洋有机磷酸酯及其生物富集研究进展[J].海洋科学,2025,49(12):92-103,12.基金项目
辽宁省科技计划联合计划(自然科学基金-面上项目)(2025-MSLH-131) (自然科学基金-面上项目)
辽宁省教育厅高校基本科研项目(JYTMS20230498) (JYTMS20230498)
国家环境保护近岸海域生态环境重点实验室开放研究课题基金(202305) (202305)
大连海洋大学引进人才博士启动项目(HDYJ202121)Liaoning Provincial Science and Technology Plan Joint Pro-gram(Natural Science Foundation-General Program),No.2025-MSLH-131 (HDYJ202121)
the Basic Research Funding Project of Liaoning Provincial Education De-partment,No.JYTMS20230498 ()
the State Environmental Protection Key Laboratory of Coastal Ecosystem Open Project Fund of China,No.202305 ()
the Research Foundation for Talented Scholars of Dalian Ocean University,No.HDYJ202121 ()