南京工业大学学报（自然科学版）2026，Vol.48Issue(1)：42-51,10.DOI:10.3969/j.issn.1671-7627.2026.01.004
苯酚加氢制环己酮催化反应过程研究进展
Progress in the catalytic hydrogenation of phenol to cyclohexanone
摘要
Abstract
Cyclohexanone is an important organic intermediate mainly used to produce adipic acid and caprolactam.The hydrogenation of phenol to cyclohexanone has attracted considerable attention because it features a short process flow,minimal by-products,and low energy consumption.This study summarizes recent progress in slurry-bed,fixed-bed,and catalytic membrane reactors used in phenol hydrogenation.For slurry-bed reactors,the discussion highlights progress in development of hydrogen sources,regulation of the reaction atmosphere,and catalyst separation.For fixed-bed reactors,the study outlines their applications in gas-phase phenol hydrogenation and describes recent progress in continuous-flow fixed-bed reactors and fixed-bed reactors coupled with membrane dispersion for liquid-phase hydrogenation.The current development of catalytic membrane reactors,particularly their ability to integrate catalytic reactions with in situ separation of catalysts and products,is also discussed.Based on these progresses,future research directions for the catalytic hydrogenation of phenol to cyclohexanone are proposed.关键词
苯酚/催化加氢/环己酮/浆态床反应器/固定床反应器/催化膜反应器Key words
phenol/catalytic hydrogenation/cyclohexanone/slurry-bed reactor/fixed-bed reactor/catalytic membrane reactor分类
化学化工引用本文复制引用
张春花,张久选,姜红,陈日志..苯酚加氢制环己酮催化反应过程研究进展[J].南京工业大学学报（自然科学版）,2026,48(1):42-51,10.基金项目
2023年江苏高校"青蓝工程"中青年学术带头人项目(苏教师函[2023]27号) （苏教师函[2023]27号）
2023年江苏高校"青蓝工程"优秀教学团队项目(苏教师函[2023]27号) （苏教师函[2023]27号）
江苏省高等学校自然科学研究项目(25KJA540001) （25KJA540001）
