山东科学2026，Vol.39Issue(2)：62-73,12.DOI:10.3976/j.issn.1002-4026.2025140
稀土掺杂钨酸钴纳米纤维的合成及光热协同光催化性能研究
Rare-earth-doped cobalt tungstate nanofibers:Synthesis and photothermal-enhanced full-spectrum photocatalysis
摘要
Abstract
To achieve efficient utilization of the full solar spectrum and enhance the photocatalytic performance of cobalt tungstate(CoWO4),one-dimensional CoWO4 nanomaterials doped with rare-earth(RE)elements(Ce3+,Eu3+,Yb3+,and La3+)were synthesized using electrospinning technology.The structural,morphological,photocatalytic,and photothermal sterilization properties of the synthesized nanomaterials were systematically investigated.X-ray diffraction analysis revealed that all samples retained the monazite monoclinic structure of wolframite,with RE doping inducing lattice distortion.Scanning electron microscopy and transmission electron microscopy results demonstrated that doping increased the surface roughness of the nanotubes and generated a porous structure,thereby providing more active sites for reactions.Photocatalytic performance tests showed that 7％Ce-CoWO4 achieved a degradation rate of 90.54％for ciprofloxacin under visible light within 140 min and 81.84％under near-infrared(NIR)light within 7 h.Electrochemical tests indicated that RE doping effectively reduced charge-transfer resistance and enhanced the photocurrent response.In terms of photothermal performance,5％Yb-CoWO4 increased the temperature of the liquid system to 65℃ within 360 s under NIR irradiation,demonstrating excellent photothermal conversion capability.Antimicrobial experiments confirmed that the re-doped samples exhibited significant photothermal sterilization effects against Escherichia coli under NIR irradiation.This study provides new insights into the development of efficient,multifunctional photocatalytic materials with full-spectrum response capabilities.关键词
全光谱/钨酸钴/光催化/静电纺丝/稀土掺杂/光热杀菌/晶格畸变Key words
full solar spectrum/CoWO4/photocatalytic performance/electrospinning/rare-earth-doped/photothermal antibacterial/lattice distortion分类
信息技术与安全科学引用本文复制引用
王可,郭恩言,卢启芳,郝霄鹏..稀土掺杂钨酸钴纳米纤维的合成及光热协同光催化性能研究[J].山东科学,2026,39(2):62-73,12.基金项目
国家自然科学基金(52472216) （52472216）
济南市高校创新团队项目(202228023) （202228023）
