石油化工2026，Vol.55Issue(4)：593-602,10.DOI:10.3969/j.issn.1000-8144.2026.04.015
镍配合物催化的α-烯烃聚合研究进展
Research progress on α-olefin polymerization catalyzed by Ni complexes
刘欣悦 1李玉莲 2俞越 2陈林枫 2孙文华3
作者信息
- 1. 北京低碳清洁能源研究院,北京 102211||中国科学院 化学研究所 工程塑料重点实验室,北京 100190
- 2. 北京低碳清洁能源研究院,北京 102211
- 3. 中国科学院 化学研究所 工程塑料重点实验室,北京 100190
- 折叠
摘要
Abstract
The market demand for high-end polyolefins and high-end synthetic lubricants has increased continuously,drawing significant attention to the polymerization of long-chain α-olefin.The catalysts serve as one of the key factors in the polymerization process.With unique chain walking capability,late-transition metal catalysts show great potential for developing brand-new polyolefin materials.Among those catalysts,nickel complex catalysts are much more widely used thanks to the cost-effectiveness.With a focus on the application of nickel complex catalysts in α-olefin polymerization,recent research advances in this field are reviewed,including the catalytic activity of nickel complex catalysts with various structures,the polymer microstructures,and the correlation between the polymer microstructures and macroscopic properties.Perspectives on the future development of this field are also provided.关键词
镍配合物催化剂/链行走/α-烯烃聚合/聚合物微结构Key words
Ni complex catalyst/chain walking/α-olefin polymerization/polymer microstructure分类
化学化工引用本文复制引用
刘欣悦,李玉莲,俞越,陈林枫,孙文华..镍配合物催化的α-烯烃聚合研究进展[J].石油化工,2026,55(4):593-602,10.
