新型炭材料（中英文）2026，Vol.41Issue(2)：379-392,14.DOI:10.1016/S1872-5805(26)61071-2
煤基活性炭双杂原子掺杂的协同机制及其储锌性能提升
The doping of coal-based activated carbon with both B and N for use as the cathode of high performance aqueous zinc-ion hybrid capacitors
摘要
Abstract
Aqueous zinc-ion capa-citors(ZICs)have significant po-tential as energy storage systems because of their high specific ca-pacity and superior reliability.Het-eroatom-doped carbon materials were known to substantially in-crease the capacitance of ZICs,however the mechanism remains poorly understood.Coal-based ac-tivated carbon was functionalized with B and N to serve as the cath-ode material in ZICs.This modi-fication gave the material a high specific capacity of 371.4 mAh g-1 at 1 A g-1 and it retained 74%of its initial capacity after 10 000 cycles.Experimental results and density functional theory calculations revealed that pyridinic N plays a crucial role in increasing Zn2+storage,demonstrat-ing superior electrochemical reversibility.This work gives valuable insight into the design of high-capacity and ultrafast pseudocapacitive carbon cathodes for ZICs.关键词
杂原子掺杂/锌离子电容器/煤基活性炭/正极材料Key words
Heteroatom doping/Zinc-ion capacitor/Coal based activated carbon/Cathode分类
化学化工引用本文复制引用
刘淑源,田真,王延忠,周瑞,郑智超..煤基活性炭双杂原子掺杂的协同机制及其储锌性能提升[J].新型炭材料（中英文）,2026,41(2):379-392,14.基金项目
This work was supported by National Natural Science Foundation of China(52202051),the Key Re-search and Development(R&D)Projects of Shanxi Province(202202040201005).The authors extend their gratitude to Zhang Huifang(from Scientific Compass www.shiyanjia.com)for providing invalu-able assistance with the measurement analysis. 国家自然科学基金项目(52202051) （52202051）
山西省重点研发项目(202202040201005). （202202040201005）
