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石化企业典型排放源VOCs排放特征及其环境影响评价

彭金蝉 冯云霞 蒙毅 亓海军 郭一蓉 王好 肖安山

安全、健康和环境2026,Vol.26Issue(4):27-34,8.
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安全、健康和环境2026,Vol.26Issue(4):27-34,8.DOI:10.3969/j.issn.1672-7932.2026.04.005

石化企业典型排放源VOCs排放特征及其环境影响评价

Emission Characteristics and Environmental Impact Assessment of VOCs from Typical Emission Sources of Petrochemical Enterprises

彭金蝉 1冯云霞 1蒙毅 2亓海军 2郭一蓉 1王好 3肖安山1

作者信息

  • 1. 化学品安全全国重点实验室,山东 青岛 266104||中石化安全工程研究院有限公司,山东 青岛 266104
  • 2. 中国石油化工股份有限公司济南分公司,山东 济南 250101
  • 3. 暨南大学环境与气候学院,广东 广州 511443
  • 折叠

摘要

Abstract

To investigate the emission characteristics and environmental impact of volatile organic com-pounds(VOCs),this study monitored 116 VOCs species across six production units,including the catalytic cracking unit,at a petrochemical enterprise in East China.The results indicated that the catalytic reforming unit exhibited the highest concentration of total VOCs(TVOCs)at 1 544.17 μg/m3.Alkanes were the dominant pollutants,contributing 34.5%to 79.8%of the total emissions across all units,with low-carbon alkanes such as ethane and propane showing consistently high concentrations.Furthermore,alkenes and aromatics demonstra-ted the highest contribution to ozone formation,with m/p-xylene,o-xylene,and propylene identified as critical precursors.Aromatics also constituted the largest contributors to secondary organic aerosol(SOA)formation across all units(70.5%~92.3%),among which benzene,toluene,and o-xylene emerged as the key reactive species.Overall,while the enterprise′s current VOCs emission levels are moderate,the treatment of low-carbon alkanes should be further enhanced to reduce general VOCs pollution.Consequently,strict emission controls on specific high-risk substances,notably acrolein,benzene,and o-xylene,must be implemented to effectively mit-igate their environmental impact.

关键词

挥发性有机物/石化园区/排放特征/二次有机气溶胶/臭氧生成潜势

Key words

volatile organic compounds/petrochemical park/emission characteristics/secondary organic aerosol/ozone formation potential

分类

资源环境

引用本文复制引用

彭金蝉,冯云霞,蒙毅,亓海军,郭一蓉,王好,肖安山..石化企业典型排放源VOCs排放特征及其环境影响评价[J].安全、健康和环境,2026,26(4):27-34,8.

基金项目

中国石化科技部项目(324005),石化企业典型异味源臭气浓度定量表征技术及装备研究. (324005)

安全、健康和环境

1672-7932

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