东华大学学报（英文版）2026，Vol.43Issue(2)：43-50,8.DOI:10.19884/j.1672-5220.202509002
MOF负载二亚胺镍催化高活性丙烯二聚反应
MOF-Supported Diimine-Ni Catalyzed Highly Active Propylene Dimerization
摘要
Abstract
A heterogeneous diimine-Ni catalyst(diimine-Ni@PCN-701)is synthesized through sequential ligand insertion into PCN-700,a robust Zr-based metal-organic framework(MOF),followed by chelation of Ni centers.This site-specific assembly affords a robust active center for propylene dimerization with superior activity,which arises from the electron-withdrawing effect of Zr6 O4(OH)4 clusters on the Ni active sites.Propylene is selectively converted into a series of dimers with 4-methyl-2-pentene(4M2P)as the main product,which may be due to the MOF structure promoting this reaction through both electronic effects and steric hindrance.This work highlights a general strategy for developing heterogeneous olefin oligomerization catalysts with high activity and shape selectivity through the precise construction of active sites.关键词
非均相催化剂/金属有机骨架(MOF)/二亚胺镍配合物/丙烯二聚Key words
heterogeneous catalyst/metal-organic framework(MOF)/diimine-Ni complex/propylene dimerization分类
化学化工引用本文复制引用
宋璐璐,陈龙,孙俊芬,李明远,王乐,蔡正国..MOF负载二亚胺镍催化高活性丙烯二聚反应[J].东华大学学报（英文版）,2026,43(2):43-50,8.基金项目
National Natural Science Foundation of China(Nos.22071023 and 22101056) （Nos.22071023 and 22101056）
Program of Shanghai Academic and Technology Research Leader,China(No.22XD1400100) （No.22XD1400100）
Fundamental Research Funds for the Central Universities,China(Nos.2232020A-05 and 2232024D-04) （Nos.2232020A-05 and 2232024D-04）
