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全氟碳化合物乳液中氧溶解度测定的改良酶促法

王兴宇 王彪 葛世杰 郭迎馨

东华大学学报(英文版)2026,Vol.43Issue(2):76-81,6.
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东华大学学报(英文版)2026,Vol.43Issue(2):76-81,6.DOI:10.19884/j.1672-5220.202410002

全氟碳化合物乳液中氧溶解度测定的改良酶促法

Determination of Oxygen Solubility in Perfluorocarbon Emulsions by a Modified Enzymatic Method

王兴宇 1王彪 1葛世杰 1郭迎馨1

作者信息

  • 1. 东华大学 先进纤维材料全国重点实验室 材料科学与工程学院,上海 201620
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摘要

Abstract

Oxygen solubility in perfluorocarbon(PFC)emulsions is a crucial performance metric in fields such as artificial blood,oxygen transportation and diagnostic imaging agents.However,there is a lack of simple and accurate detection methods.In this study,the perfluorooctyl bromide(PFOB)emulsion was prepared by using perfluorohexylethyl polyoxyethylene ether(FEO)as the emulsifier,and a modified enzymatic method was developed by using a more stable Orange G as the color indicator to determine the oxygen solubility in the PFOB emulsion at 298.15 K and atmospheric pressure.For 0.2 mL emulsion,the oxygen solubility measured by the modified enzymatic method was close to that measured by gas-liquid chromatography as reported in the literature.The effects of mass fractions of PFC and FEO in the emulsions on the oxygen solubility were studied based on the modified enzymatic method.The results indicate that the oxygen solubility in the emulsion increases with the increasing mass fraction of PFC,independent of the mass fraction of the emulsifier.

关键词

全氟碳化合物(PFC)乳液/氧溶解度/酶促法

Key words

perfluorocarbon(PFC)emulsion/oxygen solubility/enzymatic method

分类

化学化工

引用本文复制引用

王兴宇,王彪,葛世杰,郭迎馨..全氟碳化合物乳液中氧溶解度测定的改良酶促法[J].东华大学学报(英文版),2026,43(2):76-81,6.

基金项目

National Key R&D Program of China(No.2020YFB1505700) (No.2020YFB1505700)

东华大学学报(英文版)

1672-5220

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