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石榴汁碳量子点的制备及其在铁离子检测和抑菌方面的应用

李宽 范文林 管曼君 王癸龙 刘心怡 李明田

分析测试学报2026,Vol.45Issue(5):989-1000,12.
分析测试学报2026,Vol.45Issue(5):989-1000,12.DOI:10.12452/j.fxcsxb.25121704

石榴汁碳量子点的制备及其在铁离子检测和抑菌方面的应用

Preparation and Applications of Pomegranate Juice CQDs for Iron Ion Detection and Antibacterial

李宽 1范文林 1管曼君 1王癸龙 1刘心怡 1李明田2

作者信息

  • 1. 四川轻化工大学 材料科学与工程学院,四川 自贡 643000
  • 2. 四川轻化工大学 材料科学与工程学院,四川 自贡 643000||材料腐蚀与防护四川省重点实验室,四川 自贡 643000
  • 折叠

摘要

Abstract

Carbon quantum dots(CQDs)are a type of nanomaterial with excellent luminescent prop‑erties and have promising applications in various fields.Green fluorescent carbon quantum dots(g-CQDs)were synthesized by a solvothermal method using pomegranate juice as the carbon source and absolute ethanol as the solvent.The structure and optical properties of g-CQDs were characterized by UV-Vis absorption,fluorescence spectroscopy,FTIR and TEM.The results showed that g-CQDs had an average particle size of approximately 2.96 nm,with abundant surface functional groups such as hydroxyl and carboxyl groups,exhibiting good water dispersibility and fluorescence stability.Un‑der excitation at 410 nm,g-CQDs emit green fluorescence at 500 nm with a quantum yield of 15.24%.The fluorescence of g-CQDs was quenched by Fe3+and Fe2+,and the quenching mechanism mainly involves photo-induced electron transfer resulting from surface coordination.The detection limits of Fe2+are 0.155 μmol/L(linear range 1.25-18 μmol/L)and 0.221 μmol/L(linear range 18-50 μmol/L),respectively.The detection limit of Fe3+within the linear range of 2.5 to 72.5 μmol/L is 0.211 μmol/L.It can be concluded that g-CQDs has sensitivity for Fe3+and Fe2+.The antibacterial experiments indicated that g-CQDs exhibited inhibitory effects on mold growth,with the antibacteri‑al activity increasing at higher concentrations.This study provides a reference for the green synthesis of multifunctional CQDs and their applications in ion detection and antibacterial fields.

关键词

碳量子点/石榴汁/溶剂热/铁离子/抑菌

Key words

CQDs/pomegranate juice/solvothermal/iron ion/antibacterial

分类

化学化工

引用本文复制引用

李宽,范文林,管曼君,王癸龙,刘心怡,李明田..石榴汁碳量子点的制备及其在铁离子检测和抑菌方面的应用[J].分析测试学报,2026,45(5):989-1000,12.

基金项目

四川轻化工大学研究生创新基金(Y2024060,Y2025003,Y2025014) (Y2024060,Y2025003,Y2025014)

分析测试学报

1004-4957

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