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Mo合金化纯Ti电化学行为研究

高强 滕艾均 康强 王鹏 王纪兵

钢铁钒钛2026,Vol.47Issue(1):89-93,5.
钢铁钒钛2026,Vol.47Issue(1):89-93,5.DOI:10.7513/j.issn.1004-7638.2026.01.010

Mo合金化纯Ti电化学行为研究

The investigation of Mo alloying on the electrochemical behaviour of pure Ti

高强 1滕艾均 1康强 1王鹏 1王纪兵2

作者信息

  • 1. 鞍钢集团北京研究院有限公司钒钛分院,北京 102200
  • 2. 中国重型汽车集团,山东济南 250101
  • 折叠

摘要

Abstract

The effect of pure Ti alloyed with different Mo content on the microstructure and electro-chemical behaviour was studied for the need of further improvement in corrosion resistance and con-ductivity of titanium bipolar plates in proton exchange membrane water electrolysis environments.Res-ults indicated that the volume fraction of β phase increased,the grain size of α phase decreased,and the corrosion resistance was improved with the increase of Mo content.The warburg impedance appeared in the low frequency region of impedance spectroscopy obtained at open circuit potential(OCP).When the Mo content was below 1.0%,there were many corrosion pits on the surface after electrochemical corro-sionthe.Passivation film formed by polarizing at 1.0 V vs Ref for 4 hours exhibited n-type semiconduct-or behavior,and the conductivity increasesd with Mo content greater than 1.0%.

关键词

双极板/Ti/Mo/微观结构/耐蚀性

Key words

bipolar plates/Ti/Mo/microstructure/corrosion resistance

分类

矿业与冶金

引用本文复制引用

高强,滕艾均,康强,王鹏,王纪兵..Mo合金化纯Ti电化学行为研究[J].钢铁钒钛,2026,47(1):89-93,5.

基金项目

航空用大规格钛合金材料研制技术攻关(2024JH1/11700026). (2024JH1/11700026)

钢铁钒钛

1004-7638

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