广州化学2026，Vol.51Issue(2)：60-65,81,7.DOI:10.16560/j.cnki.gzhx.20252717
Vi-MQ硅树脂制备的无溶剂型有机硅压敏胶及性能
Preparation and Performance of Solvent-Free Silicone Pressure-Sensitive Adhesive Based on Vi-MQ Silicone Resin
乔锦飞 1涂园园 2曾成 1胡继文 2严殊颜 1吴继勇 1李娜3
作者信息
- 1. 中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049
- 2. 中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049||国科广化(南雄)新材料研究院有限公司,广东南雄 512400||国科广化韶关新材料研究院,广东韶关 512400||中国科学院新型特种精细化学品工程实验室,广东 广州 510650
- 3. 中国科学院广州化学研究所,广东 广州 510650||国科广化(南雄)新材料研究院有限公司,广东南雄 512400
- 折叠
摘要
Abstract
Vi-MQ silicone resins with different M/Q ratios were successfully prepared through hydrolysis and condensation using raw materials including tetraethyl orthosilicate,hexamethyldisiloxane,vinyldimethylethoxysilane,glacial acetic acid,etc.The structure and thermal properties of the synthesized Vi-MQ silicone resins were characterized by FT-IR,1H-NMR,and TGA,confirming the successful synthesis of the target resins.Solvent-free silicone pressure-sensitive adhesives(PSAs)were prepared by blending the synthesized Vi-MQ silicone resins with silicone oils.The effects of factors such as the M/Q ratio of the Vi-MQ resin,resin content,viscosity of the silicone oil,and Si-H ratio on the properties of the silicone PSAs were systematically investigated.The results indicated that the overall performance of the PSA was optimized when the M/Q ratio was 0.8,the resin content was 50％,a vinyl silicone oil with a viscosity of 200 mPa·s and a hydroxyl silicone oil with a viscosity of 500 mPa s were used,and the Si-H ratio was 1.5.Under these conditions,a 180 °peel strength of 19.32 g/25 mm and a holding time of 7.42 h were achieved.关键词
Vi-MQ硅树脂/水解缩合/无溶剂/有机硅压敏胶/剥离力Key words
Vi-MQ silicone resin/hydrolysis and condensation/solvent-free/silicone pressure-sensitive adhesive/peel strength分类
化学化工引用本文复制引用
乔锦飞,涂园园,曾成,胡继文,严殊颜,吴继勇,李娜..Vi-MQ硅树脂制备的无溶剂型有机硅压敏胶及性能[J].广州化学,2026,51(2):60-65,81,7.
