煤田地质与勘探2026，Vol.54Issue(4)：178-189,12.DOI:10.12363/issn.1001-1986.25.12.0901
煤基固废-调控剂复合改性超细水泥性能优化
Performance optimization of superfine cement through composite modification using coal-based solid waste and modifiers
摘要
Abstract
[Objective]Superfine cement-based grouting materials generally suffer from limitations including high bleed-ing rates,unfavourable rheological properties,poor stability,and strength retrogression.These issues can be mitigated by incorporating modifiers,which allows for the reutilization of coal-based solid waste while enhancing the performance of composite,superfine cement-based grouting materials.[Methods]Superfine cement-based grouting materials with dif-ferent mixing ratios were prepared by using superfine cement as the basic material,fly ash(FA)and mineral fines(MFs)as primary admixtures,and modified bentonite,methyl cellulose ether(MCE),U-type expansive agent(UEA),and mag-nesium oxide(MgO)as modifiers.These grouting materials and pure superfine cement were examined using macroscop-ic performance analyses,including tests of grout rotational viscosity,compressive strength experiments,and groutability tests.In ccombination with microscopic analysis through scanning electron microscopy(SEM),this study systematically investigated the laws of impacts of different mixing schemes on the fluidity,stability,peak hydration temperature,and mechanical strength of composite grout.[Results and Conclusions]Various admixtures and their ratios exhibited signi-ficant nonlinear superimposition effects on the bleeding rate and stability of grout.Specifically,MCE enhanced the sta-bility of grout but inhibited its mobility.The coal-based solid waste admixtures effectively reduced the peak hydration temperature of grout,with a maximum decrease of 48.6％.UEA and MCE delayed the onset of peak hydration temperat-ure by 1-4 hours.In terms of mechanical properties,the bentonite-modified systems yielded superior 28-day compress-ive strength compared to MCE-modified systems.UEA outperformed MgO in shrinkage compensation and late-stage strength enhancement,while also mitigating the strength retrogression observed in the pure cement system.Grouting tests demonstrate that the mixing ratio scheme comprising 70％superfine cement,20％FA,and 10％MFs,combined with 10％UEA and 5％bentonite,exhibited the optimal diffusion performance,bonding property,and cost efficiency.The results of this study can provide a reference for enhancing the performance of modified cement-based materials and promoting the high-value utilization of coal-based solid waste.关键词
煤基固废/超细水泥/可灌性分析/微观结构/复合改性/控制变量法Key words
coal-based solid waste/superfine cement/groutability analysis/microstructure/composite modification/controlled variable method分类
资源环境引用本文复制引用
康志鹏,罗勇,肖殿才,任帅,蔡志良,高翔,张坤哲..煤基固废-调控剂复合改性超细水泥性能优化[J].煤田地质与勘探,2026,54(4):178-189,12.基金项目
国家科技重大专项课题(2024ZD1004108) （2024ZD1004108）
安徽省重点研究和开发计划项目(201904a07020011) （201904a07020011）
