煤矿安全2026，Vol.57Issue(4)：49-60,12.DOI:10.13347/j.cnki.mkaq.20250899
新型复合微胶囊阻化剂的制备及性能研究
Preparation and performance study of a novel composite microcapsule inhibitor
摘要
Abstract
Aiming at the problems of strong hygroscopy,easy decomposition and deactivation,and poor storage stability existing in traditional inhibitors,a novel polyethylene glycol(PEG)-based composite microcapsule inhibitor was developed to improve its envir-onmental stability and inhibition effect on coal spontaneous combustion.Taking the composite system of citric acid(CA)and am-monium polyphosphate(APP)as the core material and polyethylene glycol 20000(PEG20000)as the wall material,the optimal mass ratio of core material was determined as m(CA)∶m(APP)=1∶5 via screening with a cone calorimeter,and microcapsule inhibit-ors with core-wall ratios of 1∶1,1∶2,1∶3 and 2∶1 were prepared by the melt-dispersion condensation method.The characteriza-tion results of scanning electron microscope(SEM)and energy dispersive spectrometer(EDS)showed that a continuous colloidal PEG film was formed on the surface of the microcapsules,and only the wall material elements were detected in the EDS spectra,which confirmed that the core material was successfully encapsulated by PEG20000.The results of thermogravimetric-differential scanning calorimetry(TG-DSC)experiments indicated that the sample with a core-wall ratio of 1∶1(B2)exhibited the best inhibi-tion performance:its critical temperature t1 and dry cracking temperature t2 were increased by 24.95%and 40.22%compared with raw coal,the thermal equilibrium temperature was delayed by 19.45℃,the heat absorption capacity was increased by 357.00 J/g,and the heat release capacity was reduced by 898.53 J/g,which significantly delayed the exothermic process of coal oxidation.The results of constant temperature and humidity experiments(RH=70%/60%,25℃)showed that the moisture absorption rate of the B2 sample was reduced by 20.33%and 19.87%compared with the core material inhibitor,respectively,indicating a significant improve-ment in its environmental stability.Further analysis via programmed temperature rise and Fourier transform infrared spectroscopy(FTIR)demonstrated that the maximum CO generation rate of the coal sample treated with the B2 sample was reduced by 72.78%compared with raw coal,with the inhibition rate reaching 70.09%at 100℃;meanwhile,the peak area proprtions of aliphatic hydro-carbon groups(-CH3/-CH2-)and hydroxyl groups(-OH)were reduced by 2.38%and 3.51%compared with raw coal,respectively,while the peak area proprtions of ether bonds(C-O)was increased by 5.73%.关键词
煤自燃/微胶囊阻化剂/材料制备/阻化特性/官能团Key words
coal spontaneous combustion/microcapsule inhibitor/material preparation/inhibition characteristics/functional groups分类
矿业与冶金引用本文复制引用
吴群群,张雷林,季燕男,刘金峰..新型复合微胶囊阻化剂的制备及性能研究[J].煤矿安全,2026,57(4):49-60,12.基金项目
国家自然科学基金资助项目(52474202,51874008) （52474202,51874008）
安徽省自然科学基金杰青资助项目(2408085J032) （2408085J032）
