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磷酸铁锂/碳气凝胶复合正极制备及其储能机制研究

尤露媛 张舒茜 乔志军 于学文 阮殿波

电源技术2026,Vol.50Issue(5):810-817,8.
电源技术2026,Vol.50Issue(5):810-817,8.DOI:10.3969/j.issn.1002-087X.2026.05.004

磷酸铁锂/碳气凝胶复合正极制备及其储能机制研究

Preparation of LiFePO4/carbon aerogel composite cathode and its energy storage mechanism

尤露媛 1张舒茜 1乔志军 1于学文 2阮殿波1

作者信息

  • 1. 宁波大学机械工程与力学学院,浙江 宁波 315211||全省特种电化学储能电源重点实验室,浙江 宁波 315211
  • 2. 宁波工程学院新能源学院,浙江 宁波 315112
  • 折叠

摘要

Abstract

To enhance electrochemical performance,LiFePO4(LFP)was composited with carbon aero-gel(CA),leveraging its high specific surface area and porous structure.This work specifically investi-gates the effects of two key physical properties—LFP particle size and CA's specific surface area—on the composite's performance.Experiments demonstrate that the composite electrode constructed with small-sized LFP and high-specific-surface-area CA exhibits excellent comprehensive perfor-mance,delivering an initial discharge specific capacity of up to 165.5 mAh/g with an initial Coulom-bic efficiency of 100.0%,and maintaining a high capacity retention rate of 94.6%after 500 cycles.This result clearly verifies the significant impact of raw materials'physical properties on the electro-chemical performance of the composite and provides an important optimization basis for the subse-quent design of high-performance LFP/CA composite electrodes.

关键词

磷酸铁锂/碳气凝胶/复合正极/耦合协同储能/物理参数调控

Key words

LiFePO4/carbon aerogel/composite material/synergistic effect/specific surface area

分类

信息技术与安全科学

引用本文复制引用

尤露媛,张舒茜,乔志军,于学文,阮殿波..磷酸铁锂/碳气凝胶复合正极制备及其储能机制研究[J].电源技术,2026,50(5):810-817,8.

电源技术

1002-087X

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