燃料化学学报（中英文）2026，Vol.54Issue(5)：107-124,18.DOI:10.1016/S1872-5813(26)60652-4
荧光纳米成像破解工业分子筛催化剂"黑箱":传质-酸性-积炭机理与优化设计
Fluorescence nanoscopy unveils the black box of industrial zeolite catalysts:Mechanisms and optimization of mass transfer-acidity-coke formation
摘要
Abstract
The performance of industrial zeolite catalysts,typically exemplified by fluid catalytic cracking(FCC)catalysts,is governed by microscopic behaviors such as mass transfer,acidity and coking.Conventional characterization techniques exhibit limitations in elucidating the structure-performance relationships.So,recent advances in super-resolution fluorescence imaging for deciphering the key microscopic processes are systematically summarized in this review:(1)Mass transfer diffusion behavior:the heterogeneous diffusion of reactant molecules within hierarchical pore networks are revealed;(2)Acid site accessibility:nanoscale localization of acid sites and visualization of their accessibility are achieved;(3)Coking behavior:the spatiotemporal evolution mechanism of coke species on the catalysts are identified.Furthermore,the review elaborates on how super-resolution imaging deepens the understanding of fundamental catalytic mechanisms at the nanoscale,providing theoretical support for the rational design of high-performance catalysts-such as pore structure optimization,acid site regulation,and coking suppression-and concludes with an outlook on current challenges and future directions.关键词
超分辨荧光成像技术/分子筛催化剂/传质扩散/酸中心/积炭Key words
super-resolution fluorescence imaging/zeolite catalysts/mass transfer diffusion/acid sites/coking分类
化学化工引用本文复制引用
关慧敏,唐琴,张君屹,张梅花,黄义星,王焕,段宏昌,秦玉才,宋丽娟..荧光纳米成像破解工业分子筛催化剂"黑箱":传质-酸性-积炭机理与优化设计[J].燃料化学学报（中英文）,2026,54(5):107-124,18.基金项目
Supported by National Natural Science Foundation of China(2023YFAI150770),Liaoning Revitalization Talents Program(XLYC2203165),Department of Education of Liaoning Province(LJ212510148027),the Talent Scientific Research Fund of LSHU(2024XJJL-001),PetroChina Lanzhou Petrochemical Company(LZSH-2025-JS-67)and Department of Science and Technology of Liaoning Province(2025-MSLN-443). （2023YFAI150770）
