陕西科技大学学报2026，Vol.44Issue(3)：99-106,117,9.
富勒烯晶格限域PtFeCoNiRu高熵合金催化剂的制备及其电解水析氢性能
Preparation of fullerene-confined PtFeCoNiRu high-entropy alloy catalyst and its performance for electrocatalytic hydrogen evolution reaction
摘要
Abstract
Electrochemical water splitting is one of the primary methods for producing"green hydrogen,"but the slow kinetics of the cathodic hydrogen evolution reaction(HER)heavily rely on efficient catalysts.Although platinum(Pt)-based noble metal catalysts exhibit excel-lent performance,their high cost and scarcity limit large-scale application.Therefore,develo-ping HER catalysts with low noble metal loading and high activity is of great significance.In this study,a ruthenium(Ru)-based high-entropy alloy catalyst confined within a fullerene lattice,PtFeCoNi/Ru@CFN,was successfully prepared via multi-metal co-reduction and high-temperature sintering.In 1 M KOH alkaline electrolyte,the catalyst requires an overpo-tential of only 31 mV to achieve a current density of 10 mA cm-2.At an overpotential of 0.1 V,its mass activity is 16.9 times higher than that of commercial Pt/C,and it demonstrates excellent stability,maintaining continuous operation for over 40 hours.Structural character-ization and electrochemical tests indicate that the introduction of Ru further optimizes the e-lectronic structure,and the synergistic effect of the multi-metal alloy significantly enhances the intrinsic activity.This study provides a new strategy for designing low-cost,high-per-formance HER catalysts with strong potential for practical applications.关键词
高熵合金/富勒烯/电催化剂/制氢/电解水Key words
high-entropy alloy/fullerene/electrocatalyst/hydrogen production/water electrolysis分类
化学化工引用本文复制引用
陈宇龙,冯永强,张梦怡,强晋源,高术涵,卫莹,刘毅,查奕帆..富勒烯晶格限域PtFeCoNiRu高熵合金催化剂的制备及其电解水析氢性能[J].陕西科技大学学报,2026,44(3):99-106,117,9.基金项目
国家自然科学基金项目(52572048) （52572048）
陕西科技大学大学生创新创业训练计划项目(202410708018) （202410708018）
