塑料科技2026，Vol.54Issue(5)：192-197,6.DOI:10.15925/j.cnki.issn1005-3360.2026.05.035
α-二亚胺镍/钯配合物催化乙烯聚合的研究进展
Research Progress on Ethylene Polymerization Catalyzed by α-Diimide Nickel/Palladium Complexes
摘要
Abstract
Polyethylene(PE)is a thermoplastic resin that exhibited excellent impact resistance,abrasion resistance,weather resistance,lubricity,and chemical resistance.By regulating the reaction conditions and complex structures,α-diimine-coordinated late-transition metal nickel and palladium complexes not only polymerized ethylene to produce PE with different topological structures and unique properties,but also achieved the copolymerization of ethylene with polar monomers to obtain functionalized PE.The article reviewed the research progress in the preparation of branched PE through ethylene polymerization catalyzed by α-diimine nickel and palladium metal complexes over the past five years.关键词
乙烯/α-二亚胺/镍配合物/钯配合物/聚乙烯Key words
Ethylene/α-diimine/Nickel complex/Palladium complex/Polymerization分类
化学化工引用本文复制引用
张志超,刘奕含,尹馨兰,韩双..α-二亚胺镍/钯配合物催化乙烯聚合的研究进展[J].塑料科技,2026,54(5):192-197,6.基金项目
辽宁省自然基金面上项目(2022-MS-293) （2022-MS-293）
