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生物质基缓释尿素的制备及其缓释性能研究

王洁 倪杰 赵章有 吴可荆 鲁厚芳

低碳化学与化工2026,Vol.51Issue(5):68-76,9.
低碳化学与化工2026,Vol.51Issue(5):68-76,9.DOI:10.12434/j.issn.2097-2547.20250203

生物质基缓释尿素的制备及其缓释性能研究

Preparation and slow-release performance of biomass-based slow-release urea

王洁 1倪杰 2赵章有 2吴可荆 3鲁厚芳1

作者信息

  • 1. 四川大学化学工程学院,四川成都 610065
  • 2. 四川泸天化股份有限公司,四川泸州 646300
  • 3. 四川大学新能源与低碳技术研究院,四川成都 610207
  • 折叠

摘要

Abstract

The existing slow-release urea commonly faces issues such as high production costs and environmental pollution caused by degradation products,which limit their application in agricultural production.Consequently,developing efficient and cost-effective slow-release urea with environmentally friendly characteristics is the direction for the development of slow-release fertilizers.Biomass-based slow-release urea(B-SRU)was prepared by physical mixing,using four biomasses with different growth forms as raw materials.The differences in slow-release performance of different B-SRU were systematically compared and analyzed.The results show that the slow-release performance of different B-SRU exhibits significant variations in response to preparation temperatures due to the differences in structures and compositions of biomass raw materials.With the increase of preparation temperatures,the slow-release performance of herbaceous B-SRU gradually improves and the urea release rate can be reduced by 33.01%.The slow-release performance of woody B-SRU shows a gradually decreasing trend,and the slow-release performances of vine and hemp B-SRU show"V"and inverted"V"patterns in change,respectively.SEM and FTIR characterization results confirm that the binding mechanism between biomass and urea is mainly a dual action of physical dense wrapping and hydrogen bonding network.The release kinetics analysis shows that the release of urea from B-SRU is mainly dominated by classical Fick diffusion,and the urea molecules mainly migrate by diffusion through the physical pores of the biomass matrix.

关键词

生物质/缓释尿素/缓释性能/释放动力学

Key words

biomass/slow-release urea/slow-release performance/release kinetics

分类

化学化工

引用本文复制引用

王洁,倪杰,赵章有,吴可荆,鲁厚芳..生物质基缓释尿素的制备及其缓释性能研究[J].低碳化学与化工,2026,51(5):68-76,9.

基金项目

四川大学与宜宾市人民政府合作基金(2020CDYB-34). (2020CDYB-34)

低碳化学与化工

1001-9219

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