南华大学学报（自然科学版）2026，Vol.40Issue(1)：9-15,80,8.DOI:10.19431/j.cnki.1673-0062.2026.01.002
Mo0协同Fe3+活化过氧乙酸降解水中罗丹明B研究
Study on the degradation of rhodamine B in wastewater by activation of peracetic acid with Mo0 and Fe3+
摘要
Abstract
The advanced oxidation processes utilizing the activation of peracetic acid(PAA)to generate reactive oxygen species for the degradation of organic pollutants has been exten-sively studied in the past few years.This study verified the effectiveness of PAA activation for degrading Rhodamine B(RhB)in wastewater.The system used Fe3+and Mo0 as homo-geneous and heterogeneous catalysts,respectively,while PAA acted as an oxidant.It ex-amined the RhB removal under various conditions,optimizing several key parameters,e.g.,types of catalysts,initial pH,the dosage of Mo0,and concentrations of Fe3+and PAA.The results indicated that Mo0 synergistically combined with Fe3+could effectively degrade RhB.The optimal conditions were found to be 5.87 of initial pH,0.5 g/L of Mo0,0.1 mmol/Lof Fe3+,and 0.5 mmol/L of PAA.The presence of Cl-and NO-3 in the reaction system had little effect on the RhB removal,whereas HCO-3 and H2 PO-4 signifi-cantly inhibited the degradation process.Besides,the Mo0 showed a good stability.Quenching experiments demonstrated that both free radicals and non-radical reactive species were generated in the reaction system.关键词
过氧乙酸/催化剂/Mo0/Fe3+/罗丹明BKey words
peracetic acid/catalyst/Mo0/Fe3+/RhB(rhodamine B)分类
化学化工引用本文复制引用
罗才武,吕静,张贻良,蒋亮..Mo0协同Fe3+活化过氧乙酸降解水中罗丹明B研究[J].南华大学学报（自然科学版）,2026,40(1):9-15,80,8.基金项目
湖南省自然科学基金项目(2025JJ700164) （2025JJ700164）
湖南省教育厅重点项目(2024A0315) （2024A0315）
