大学化学2026,Vol.41Issue(6):362-373,12.DOI:10.12461/PKU.DXHX202503106
利用唯物主义理论对铅在多晶金电极上的欠电位沉积行为研究及痕量铅电化学分析实验教学研究
Investigation of underpotential deposition behavior of lead on polycrystalline gold electrodes using materialist theory and its application in experimental teaching of trace lead electrochemical analysis
摘要
Abstract
This study employs underpotential deposition coupled with square wave voltammetry for the electroanalytical determination of trace lead in aqueous samples.The electrochemical phenomena are systematically interpreted through the lens of materialist theory,complemented by principles of physical chemistry and electrochemistry.The research examines the underpotential deposition process,two-dimensional phase formation,bulk deposition of lead,and concentration-dependent effects.Designed as a comprehensive analytical chemistry experiment,this approach demonstrates robust theoretical foundations and practical feasibility.The problem-oriented teaching methodology,integrated with materialist theory,significantly enhances the pedagogical effectiveness of experimental instruction.关键词
辩证唯物主义理论/铅/欠电位沉积/多晶金电极/电分析研究Key words
Dialectical materialism/Lead/Underpotential deposition/Polycrystalline gold electrode/Electroanalysis分类
社会科学引用本文复制引用
杜永令,徐世浩,明岩,张正,王钇雄,时雪钊,赵永青..利用唯物主义理论对铅在多晶金电极上的欠电位沉积行为研究及痕量铅电化学分析实验教学研究[J].大学化学,2026,41(6):362-373,12.基金项目
兰州大学教学项目(JYXM(一般项目-化学)-2020-2001) (JYXM(一般项目-化学)