含能材料2026，Vol.34Issue(6)：708-729,22.DOI:10.11943/CJEM2026029
含能材料前沿热点:富氮稠环化合物的结构设计与协同优化研究进展
Advances in Structural Design and Synergistic Optimization of Nitrogen-rich Fused-ring Compounds:A Frontier in Energetic Materials
唐长伟 1何丹 1葛忠学 1贺金峰 1张茹新 1王晓莹1
作者信息
- 1. 甘肃银光化学工业集团有限公司,甘肃 白银 730999
- 折叠
摘要
Abstract
The inherent conflict between high energy density and low mechanical sensitivity represents a central challenge in the field of energetic materials.Although traditional nitramine compounds such as RDX,HMX,and CL-20 have significantly en-hanced energy levels,they remain constrained by this trade-off.To explore new pathways for overcoming conventional perfor-mance limitations,researchers have proposed a strategy centered on rigid,planar fused-ring frameworks,leading to the develop-ment of nitrogen-rich fused-ring compounds.This review systematically outlines the evolution of this field,from the design of monocyclic systems(e.g.,azoles,azines,and 1,2,5-oxadiazoles)to the integrated design of binary fused-ring systems.It high-lights the conceptual design of representative molecules,key advances in synthetic methodologies—ranging from oxidative nitra-tion to controlled rearrangement reactions—and the regulatory mechanisms of intermolecular interactions such as hydrogen-bonding networks and π-π stacking on material performance.This progression illustrates a paradigm shift from empiri-cal trial-and-error to rational design and function-oriented customization.Finally,addressing the synthetic bottlenecks that con-strain practical application,this review proposes that future breakthroughs require synergistic efforts across three dimensions:de-sign,preparation,and application.This includes developing design methods that balance performance with synthetic feasibility,promoting synthetic technologies with improved safety profiles,and expanding the application scope of fused-ring energetic ma-terials,thereby facilitating the transition from molecular design to practical implementation and providing a foundation for next-generation high-performance energetic materials.关键词
含能材料/富氮稠环化合物/稳定性/合成策略/构效关系Key words
energetic materials/nitrogen-rich fused-ring compounds/stability/synthetic methodology/structure-property relation-ship分类
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唐长伟,何丹,葛忠学,贺金峰,张茹新,王晓莹..含能材料前沿热点:富氮稠环化合物的结构设计与协同优化研究进展[J].含能材料,2026,34(6):708-729,22.
