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铜冶炼渣中铜、铁高效回收技术研究进展

高云川 马士淋 符海桃 李祥 宋强 童雄 谢贤 张文杰

铜业工程Issue(3):1-13,13.
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铜业工程Issue(3):1-13,13.DOI:10.3969/j.issn.1009-3842.2026.03.001

铜冶炼渣中铜、铁高效回收技术研究进展

Technology Development for Efficient Recovery of Copper and Iron from Copper Smelting Slag

高云川 1马士淋 2符海桃 1李祥 3宋强 4童雄 3谢贤 3张文杰5

作者信息

  • 1. 云南华联锌铟股份有限公司,云南 文山 663701||昆明理工大学 国土资源工程学院,云南 昆明 650031
  • 2. 云南锡铟实验室有限公司,云南 昆明 650200
  • 3. 昆明理工大学 国土资源工程学院,云南 昆明 650031
  • 4. 云南锡铟实验室有限公司,云南 昆明 650200||昆明理工大学 国土资源工程学院,云南 昆明 650031
  • 5. 昆明冶金研究院有限公司,云南 昆明 650021
  • 折叠

摘要

Abstract

Copper smelting slag,the primary solid waste generated from pyrometallurgical copper production,is rich in valuable metals such as Cu(0.5%~4.6%)and Fe(30%~49%),making it a significant secondary resource for recovery.However,over 80%of the global copper slag is still disposed of by stockpiling,which not only occupies land resources but also poses environmental threats due to the migration and release of toxic elements like Pb and As.Efficient recovery of copper and iron from copper slag is therefore of great significance for ensuring resource security and promoting the green transformation of the nonferrous metals industry.This paper systematically reviewed physicochemical properties and mineralogical characteristics of copper smelting slag,and provided an in-depth analysis of technical principles and research status of various processes,including flotation,pyrometallurgy(reducing roasting-magnetic separation,smelting reduction,oxidizing roasting-magnetic separation),hydrometallurgy(chemical leaching,bioleaching),and combined processes.Current technologies still face common challenges such as low copper-iron separation efficiency,low iron recovery rate,and difficulties in the full-component utilization of secondary slag.On this basis,future research is prospected to focus on the synergistic extraction mechanisms of copper and iron,low-carbon intensification technologies,and stepwise utilization of full components,aiming to provide theoretical support for resources utilization,detoxification,and high-value utilization of copper smelting slag.

关键词

铜冶炼渣/铁回收/浸出/浮选/磁选

Key words

copper smelting slag/iron recovery/leaching/flotation/magnetic separation

分类

矿业与冶金

引用本文复制引用

高云川,马士淋,符海桃,李祥,宋强,童雄,谢贤,张文杰..铜冶炼渣中铜、铁高效回收技术研究进展[J].铜业工程,2026,(3):1-13,13.

基金项目

国家自然科学基金(52364031) (52364031)

云南锡铟实验室开放课题(202405AR340002-25EA01) (202405AR340002-25EA01)

深地国家科技重大专项(2024ZD1004006) (2024ZD1004006)

铜业工程

1009-3842

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