物理化学学报2026，Vol.42Issue(7)：30-63,34.DOI:10.1016/j.actphy.2025.100225
金属有机框架(2014-2024):追求卓越性能的十年
Metal-Organic Frameworks(2014-2024):A decade pursuit for top performance
摘要
Abstract
The Nobel prize in chemistry 2025 was awarded to S.Kitagawa,R.Robson and O.M.Yaghi for the development of metal-organic frameworks(MOFs).As a star material of the 21st century,MOFs owning big specific surface areas,nanoscale porosities coupled with diverse topological structures,have been successfully applied in many fields.No longer limited to the traditional gas adsorption,separation and catalysis,MOFs,representing the state-of-the-art porous materials,have also showcased promising applications in some emerging realms,such as atmospheric water harvesting,pathogen detection,and uranium extraction from seawater.Yaghi presented a vital review on the optimal properties of MOFs before 2013 in Science;however,some remarkable breakthroughs in MOF properties have been made since then.The reticular chemistry-guided assembly of inorganic cations(nodes)with organic ligands(linkers)may lead to mixed-component MOFs with the synergistic combinations of the excellent performance from mono-component MOFs.The introduction of artificial intelligence technology into MOF fields can provide more opportunities for scientists to rapidly design and manufacture novel MOFs with tailored properties.In addition,novel porous isoreticular non-MOFs synthesized based on an inverse MOFs design strategy(negatively charged nodes and positively charged linkers)may open up a new research hotspot for MOF materials.关键词
金属有机框架/最佳性能/最优性质/新兴应用Key words
Metal-organic framework/Top-performance/Optimal property/Emerging application分类
化学化工引用本文复制引用
彭日,谢雨欣,袁帅,沈如伟,朱敦如..金属有机框架(2014-2024):追求卓越性能的十年[J].物理化学学报,2026,42(7):30-63,34.基金项目
本研究得到国家自然科学基金(21476115) （21476115）
配位化学全国重点实验室开放课题(SKLCC2504)以及材料化学工程全国重点实验室开放课题(SKL-MCE-24B03)的资助.谢雨欣感谢江苏省研究生科研与实践创新计划项目(KYCX24_1572)的支持. （SKLCC2504）
