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煅烧温度调控MoS2衍生MoO3及其对三乙胺的气敏性能

龚云鹏 马旭 胡悦 曹立久 魏丹蕊 余宗兴 陈玉放

广州化学2026,Vol.51Issue(3):38-42,5.
广州化学2026,Vol.51Issue(3):38-42,5.DOI:10.16560/j.cnki.gzhx.20252741

煅烧温度调控MoS2衍生MoO3及其对三乙胺的气敏性能

Regulation of Calcination Temperature for MoS2-Derived MoO3 and Its Gas Sensing Performance for Triethylamine

龚云鹏 1马旭 1胡悦 1曹立久 1魏丹蕊 1余宗兴 1陈玉放2

作者信息

  • 1. 中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049||中科检测技术服务(广州)股份有限公司,广东 广州 510650
  • 2. 中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049||中科检测技术服务(广州)股份有限公司,广东 广州 510650||中国科学院新型特种精细化学品工程实验室,广东 广州 510650||国科广化韶关新材料研究院,广东 韶关 512400||国科广化精细化工孵化器(南雄)有限公司,广东 南雄 512400
  • 折叠

摘要

Abstract

Using MoS2 as a precursor,MoO3 was synthesized via calcination at different temperatures,and its structural evolution was investigated for its impact on triethylamine gas sensing performance.Results indicate that as calcination temperature increases,MoS2 progressively oxidizes to MoO3.The MoO3 sample(MO-2)calcined at 400℃exhibits a rough,porous surface and demonstrates optimal gas sensing performance.Its optimum operating temperature for triethylamine detection was 150℃,exhibiting a response value of 33.33 to 50 ppm triethylamine with a selectivity coefficient of 54.4%,significantly higher than for ethanol,acetone,and other gases.This superior performance was attributed to the synergistic effects of surface reactive oxygen species and Lewis acid sites.This study provides an effective approach for constructing highly sensitive and selective MoO3-based amine gas sensing materials.

关键词

三乙胺/MoO3/煅烧温度/气敏性能

Key words

triethylamine/MoO3/calcination temperature/gas-sensing performance

分类

化学化工

引用本文复制引用

龚云鹏,马旭,胡悦,曹立久,魏丹蕊,余宗兴,陈玉放..煅烧温度调控MoS2衍生MoO3及其对三乙胺的气敏性能[J].广州化学,2026,51(3):38-42,5.

基金项目

重庆自然科学基金(CSTB2022NSCQ-MSX0986) (CSTB2022NSCQ-MSX0986)

广州化学

1009-220X

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